Polyurethanes derived from triazole-based monomers and their application as fluorescent probe for Zn2+

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorKaya, İsmet
dc.contributor.authorYeldir, Elif Karacan
dc.contributor.authorKolcu, Feyza
dc.contributor.authorNigiz, Simge
dc.date.accessioned2025-01-27T20:56:18Z
dc.date.available2025-01-27T20:56:18Z
dc.date.issued2024
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPolyurethanes are one of the most encountered polymer classes in both industry and scientific research, with their tremendous physical and chemical properties, as well as numerous advantages such as a wide range of raw materials, the ratio of groups to be used during polymerization and adjustable mechanical properties. In this study, four distinct polyurethanes were synthesized using toluene diisocyanate (TDI) and hexamethylenediisocyanate (HMDI) derived from Schiff bases formed by reacting 3,5-diamino-1,2,4-triazole (DAT) and 4 different aldehydes (2-hydroxybenzaldehyde, 4-hydroxybenzaldehyde, 2-hydroxy napthaldehyde, o-vanillin). The structural characterizations of the synthesized Schiff bases and polyurethanes were elucidated using H-1-C-13 NMR and FT-IR, thermal stability was assessed via TGA, molecular weights of the polymers were determined using GPC, electrochemical properties were evaluated by CV, and optical properties were examined using UV-Vis and fluorescence spectrophotometry. The molecular weights of polyurethanes ranged from 4500 to 10300 Da. TGA analysis of the synthesized polyurethanes demonstrated significant thermal stability, maintaining integrity up to 310 degrees C. The band gap energy (E'(g)) values of polyurethanes were found to range from 2.30 to 2.51 eV, which is lower than that of their corresponding monomers, exhibiting semiconductor properties. It was determined that DATSA-PU, one of the synthesized polyurethanes, exhibited potential as a turn-on fluorescent sensor for Zn2+ ion with a LOD value of 2.03 x 10(-7) M.
dc.identifier.doi10.1016/j.eurpolymj.2024.113483
dc.identifier.issn0014-3057
dc.identifier.issn1873-1945
dc.identifier.scopus2-s2.0-85205436539
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.eurpolymj.2024.113483
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26365
dc.identifier.volume220
dc.identifier.wosWOS:001331621700001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofEuropean Polymer Journal
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPolyurethane
dc.subjectTriazole
dc.subjectThermal Stability
dc.subjectZn fluorescent sensor
dc.subjectLOD
dc.titlePolyurethanes derived from triazole-based monomers and their application as fluorescent probe for Zn2+
dc.typeArticle

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