Kinetics and Mechanism of In(III) Ions Electroreduction on Cyclically Renewable Liquid Silver Amalgam Film Electrode: Significance of the Active Complexes of In(III)-Acetazolamide

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dc.authorid0000-0003-4607-3523en_US
dc.authorid0000-0002-2329-2451en_US
dc.authorscopusid55964006300en_US
dc.authorscopusid58180912900en_US
dc.authorwosid-en_US
dc.authorwosid-en_US
dc.contributor.authorNosal-Wiercinska, Agnieszka
dc.contributor.authorMartyna, Marlena
dc.contributor.authorPawlak, Alicja
dc.contributor.authorBazan-Wozniak, Aleksandra
dc.contributor.authorPietrzak, Robert
dc.contributor.authorYılmaz, Selehatin
dc.contributor.authorYağmur Kabaş, Sultan
dc.date.accessioned2024-01-24T06:33:34Z
dc.date.available2024-01-24T06:33:34Z
dc.date.issued2023en_US
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümü
dc.departmentMeslek Yüksekokulları, Lapseki Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümü
dc.description.abstractThe results of kinetic measurements revealed an accelerating effect of acetazolamide (ACT) on the multistep In(III) ions electroreduction in chlorates(VII) on a novel, cyclically renewable liquid silver amalgam film electrode (R–AgLAFE). The kinetic and thermodynamic parameters were determined by applying the DC polarography, square-wave (SWV) and cyclic voltammetry (CV), as well as electrochemical impedance spectroscopy (EIS). It was shown that ACT catalyzed the electrode reaction (“cap-pair” effect) by adsorbing on the surface of the R–AgLAFE electrode. The catalytic activity of ACT was explained as related to its ability to form active In(III)- acetazolamide complexes on the electrode surface, facilitating the electron transfer process. The active complexes constitute a substrate in the electroreduction process and their different structures and properties are responsible for differences in the catalytic activity. The determined values of the activation energy (Formula presented.) point to the catalytic activity of ACT in the In(III) ions electroreduction process in chlorates(VII). Analysis of the standard entropy values (Formula presented.) confirm changes in the dynamics of the electrode process.en_US
dc.identifier.citationNosal-Wiercińska, A., Martyna, M., Pawlak, A., Bazan-Woźniak, A., Pietrzak, R., Yilmaz, S., … Szabelska, A. (2023). Kinetics and Mechanism of In(III) Ions Electroreduction on Cyclically Renewable Liquid Silver Amalgam Film Electrode: Significance of the Active Complexes of In(III)—Acetazolamide. Molecules, 28(7). https://doi.org/10.3390/molecules28072942en_US
dc.identifier.doi10.3390/molecules28072942
dc.identifier.issn1420-3049
dc.identifier.issue7en_US
dc.identifier.pmid37049705
dc.identifier.scopus2-s2.0-85152330227
dc.identifier.urihttps://doi.org/10.3390/molecules28072942
dc.identifier.urihttps://hdl.handle.net/20.500.12428/5361
dc.identifier.volume28en_US
dc.identifier.wosWOS:000969799100001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorYılmaz, Selehatin
dc.institutionauthorYağmur Kabaş, Sultan
dc.language.isoen
dc.publisherMDPIen_US
dc.relation.ispartofMoleculesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rightsAttribution 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/us/*
dc.subjectActive complexesen_US
dc.subjectCatalytic activityen_US
dc.subjectIn(III) ions electroreductionen_US
dc.subjectKinetic parametersen_US
dc.subjectR–AgLAFE electrodeen_US
dc.subjectThermodynamic parametersen_US
dc.titleKinetics and Mechanism of In(III) Ions Electroreduction on Cyclically Renewable Liquid Silver Amalgam Film Electrode: Significance of the Active Complexes of In(III)-Acetazolamide
dc.typeArticle

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