Electrochemical, Spectroelectrochemical, and Electrocatalytic Dioxygen Reducing Properties of Peripheral Tetra-2,6-dimethoxyphenoxy Substituted Phthalocyanines
Yükleniyor...
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
John Wiley and Sons Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
By using of peripherally tetrakis-2,6-dimethoxyphenoxy substituted Co(II), Fe(III), and Mn(III) phthalocyanines was observed to extend the redox richness of the phthalocyanine ring with the addition of reversible metal-based electron transfer couples to the phthalocyanine ring-based electron transfer processes in solution. The emergence of highly steady anionic and cationic redox species with clear spectral and colour changes both in solution and in the film during in situ spectroelectrochemical and in situ electrocolorimetric measurements pointed out their applicability as electrochromic materials. Furthermore, the phthalocyanine complexes demonstrated strong interaction with dioxygen and thus, high electrocatalytic enforcement for its reduction.
Açıklama
Anahtar Kelimeler
Electrocatalysis, Electrochemistry, Metallophthalocyanines, Methanol-tolerant catalyst, Oxygen Reduction
Kaynak
Electroanalysis
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
33
Sayı
11
Künye
Orman, E. B., Pişkin, M., Odabaş, Z., & Özkaya, A. R. (2021). Electrochemical, Spectroelectrochemical, and Electrocatalytic Dioxygen Reducing Properties of Peripheral Tetra‐2,6‐dimethoxyphenoxy Substituted Phthalocyanines. Electroanalysis, 33(11), 2310–2322. https://doi.org/10.1002/elan.202100168
