Synthesis, molecular, and photophysicochemical characterizations of phthalocyanine dyes containing sodiumsulfonatenaphthalen-2-olate groups

Basit Öğe Kaydı
dc.authoridPişkin, Mehmet / 0000-0002-4572-4905
dc.authoridÖzturk, Ömer Faruk / 0000-0002-9244-6805
dc.contributor.authorSaruhan, Serkan
dc.contributor.authorPişkin, Mehmet
dc.contributor.authorÖzturk, Ömer Faruk
dc.contributor.authorOdabaş, Zafer
dc.date.accessioned2025-05-29T02:57:58Z
dc.date.available2025-05-29T02:57:58Z
dc.date.issued2025
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, novel highly water-soluble 6-sodiumsulfonatenaphthalen-2-olate substituted phthalocyanines from the organic near-infrared dye class and contained zinc(II) or indium(III) metal ions in their cavity, were designed, and synthesized to explore their potential use as photosensitizers in photodynamic therapy. The molecular structures of the starting materials and dyes were characterized using elemental analysis, FT-IR, UV-vis, 1H-NMR, 13C-NMR, and MALDI-TOF mass spectrometry. The solubility and aggregation behaviors of these phthalocyanine dyes have been investigated in polar solvent types such as dimethylsulfoxide and N,Ndimethylformamide, ethanol, methanol, and water, as well as in phosphate-buffered saline. They have high solubility in the studied solvents and do not show any tendency to aggregate, except for water. Their photophysical and photochemical properties were investigated in N,N-dimethylformamide. The influence of the presence and position of substituents on their macrocyclic and the nature of the metal species in their cavities on their photophysical and photochemical parameters were reported. The fluorescence properties of the zinc(II) dyes studied were enhanced, while those of indium(III) dyes were low but sufficient as photosensitizers. The suitable and sufficient photophysicochemical properties of the water-soluble near-infrared new phthalocyanine dyes denote they can be potential candidates as Type II photosensitizers for photocatalytic applications.
dc.description.sponsorshipanakkale Onsekiz Mart University Scientific Research Projects Coordination Unit [FYL-2021-3576]
dc.description.sponsorshipThis work was supported by Canakkale Onsekiz Mart University Scientific Research Projects Coordination Unit. Project Number: FYL-2021-3576.
dc.identifier.doi10.1016/j.molstruc.2025.141606
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85216856589
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2025.141606
dc.identifier.urihttps://hdl.handle.net/20.500.12428/30215
dc.identifier.volume1331
dc.identifier.wosWOS:001423331000001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250529
dc.subjectNear-infrared dye
dc.subjectWater-soluble
dc.subjectPhthalocyanine
dc.subjectPhotosensitizer
dc.titleSynthesis, molecular, and photophysicochemical characterizations of phthalocyanine dyes containing sodiumsulfonatenaphthalen-2-olate groups
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Omer Faruk Ozturk_Makale.pdf
Boyut:
5.05 MB
Biçim:
Adobe Portable Document Format
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
Çanakkale Teknik Bilimler Meslek Yüksekokulu Koleksiyonu