Poly(azomethine-epoxy-ether) containing phenyl and etoxy moieties: synthesis, characterization and fluorescence property

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridKolcu, Feyza / 0000-0002-2004-8859
dc.contributor.authorKolcu, Feyza
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:43:48Z
dc.date.available2025-01-27T20:43:48Z
dc.date.issued2018
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe design and synthesis of poly(azomethine-epoxy-ether) (PAZ-EP) containing epoxide moiety was described. The purpose of the research was the improvement of poly(azomethine-ether) containing epoxide by introduction of Schiff base moiety. PAZ-EP was synthesized using epichlorohydrin (EP). The structure of the Schiff base (SB) and PAZ-EP were verified by FT-IR, H-1-NMR, C-13-NMR and UV-Vis spectroscopic analyses. Further characterization was employed using photophysical, electrochemical and fluorescence (PL) measurements. Application of TGA and differential scanning calorimetry analyses revealed thermal stability and thus propose a thermal processibility, which makes them potential materials for many contemporary practices. The number of average molecular weight of polymer with a polydispersity index of 1.14 was found to be 6750 Da using a gel permeation chromatography instrument. The highest occupied-lowest unoccupied energy levels and electrochemical () band gap values of PAZ-EP were determined by cyclic voltammetry (CV) measurement. Scanning electron microscopy (SEM) images were illustrated at different magnifications to study the morphologic property of PAZ-EP.
dc.description.sponsorshipCanakkale Onsekiz Mart University scientific research project commission [FBA-2017-1135]
dc.description.sponsorshipThe authors thank Canakkale Onsekiz Mart University scientific research project commission for support with the Project number (Project no.: FBA-2017-1135).
dc.identifier.doi10.1007/s11696-018-0525-4
dc.identifier.endpage2832
dc.identifier.issn0366-6352
dc.identifier.issn1336-9075
dc.identifier.issue11
dc.identifier.scopus2-s2.0-85051637151
dc.identifier.scopusqualityQ2
dc.identifier.startpage2821
dc.identifier.urihttps://doi.org/10.1007/s11696-018-0525-4
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24381
dc.identifier.volume72
dc.identifier.wosWOS:000441699600013
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer International Publishing Ag
dc.relation.ispartofChemical Papers
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPoly(azomethine-ether)
dc.subjectEpichlorohydrin
dc.subjectSEM
dc.subjectPhotoluminescence
dc.titlePoly(azomethine-epoxy-ether) containing phenyl and etoxy moieties: synthesis, characterization and fluorescence property
dc.typeArticle

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