Application of a novel anthracene derivative polymer for sensitive voltammetric determination of chloramphenicol in pharmaceutical and food samples

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dc.authoridKarakaya, Serkan / 0000-0002-6401-3295
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridKolcu, Feyza / 0000-0002-2004-8859
dc.authoridDilgin, Yusuf / 0000-0002-2980-6871
dc.contributor.authorKarakaya, Serkan
dc.contributor.authorKaya, İsmet
dc.contributor.authorKolcu, Feyza
dc.contributor.authorDilgin, Yusuf
dc.date.accessioned2025-05-29T02:58:00Z
dc.date.available2025-05-29T02:58:00Z
dc.date.issued2025
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe application of new polymers for the preparation of modified electrodes is an interesting research area, which is highly significant in the electrochemical antibiotic drug sensors for food safety and environmental sides. Herein, we successfully report the synthesis of a new anthracene-based monomer (N1, N4-bis(anthracene-9-ylmethylene)-2,5-dichlorobenzene-1,4-diamine (ADCA) and Poly(ADCA) modified carbon-based electrode has been used in sensitive and selective differential pulse voltammetric determination of chloramphenicol (CPNL) for the first time. In this platform, the proposed monomer was successfully electro-polymerized onto a cheap, lowcost, and disposable pencil graphite electrode (PGE). The cyclic and differential pulse voltammetric experiments proved that the polymer-modified electrode Poly(ADCA)/PGE) has great electrocatalytic efficiency on the reduction of CPNL. The proposed platform shows a comparable performance in terms of wide linear ranges (2.0-100 and 100-1000 mu M), a low detection limit (0.55 mu M) and high sensitivity (11405 mu A mM- 1 cm- 2) by differential pulse voltammetry (DPV). Additionally, the Poly(ADCA)/PGE exhibited high selectivity and antiinterference facilities for the CPNL. The fabricated sensor showed a promising potential for the determination of CPNL in food (honey, and milk), bottled water, and pharmaceutical (eye ointment) samples with acceptable accuracies and precisions.
dc.identifier.doi10.1016/j.eurpolymj.2025.113863
dc.identifier.issn0014-3057
dc.identifier.issn1873-1945
dc.identifier.scopus2-s2.0-85218883477
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.eurpolymj.2025.113863
dc.identifier.urihttps://hdl.handle.net/20.500.12428/30238
dc.identifier.volume229
dc.identifier.wosWOS:001437438700001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofEuropean Polymer Journal
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250529
dc.subjectChloramphenicol
dc.subjectN1 N4-bis(anthracene-9-yl-methylene)-2 5-dichlorobenzene-1 4-diamine
dc.subjectPencil graphite electrode
dc.subjectDifferential pulse voltammetry
dc.subjectElectrochemical antibiotic sensors
dc.titleApplication of a novel anthracene derivative polymer for sensitive voltammetric determination of chloramphenicol in pharmaceutical and food samples
dc.typeArticle

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