Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation

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dc.authoridOzpinar, Gul/0000-0002-6913-183X
dc.authoridHacivelioglu, Ferda/0000-0002-3614-3770
dc.authoridKILIC, ADEM/0000-0003-2181-2457
dc.authoridCosut, Bunyemin/0000-0001-6530-0205
dc.contributor.authorYesilot, Serkan
dc.contributor.authorCosut, Bunyemin
dc.contributor.authorAlidagi, Husnuye Ardic
dc.contributor.authorHacivelioglu, Ferda
dc.contributor.authorOzpinar, Gul Altinbas
dc.contributor.authorKilic, Adem
dc.date.accessioned2025-01-27T20:41:47Z
dc.date.available2025-01-27T20:41:47Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA hexakis(pyrenyloxy) cyclotriphosphazene is synthesized by the reaction of N3P3Cl6 with 2-hydroxypyrene, and its excimer emission through intramolecular interactions in solution and in the solid state has been investigated by fluorescence spectroscopy and X-ray crystallography. Thermal and electrochemical properties were investigated. A DFT benchmark study has been performed to evaluate the intramolecular interactions and molecular orbital levels by comparing with the experimental results.
dc.description.sponsorshipTUBITAK [TBAG-110T142]
dc.description.sponsorshipWe wish to thank TUBITAK (project number TBAG-110T142) for financial support. We also thank TUBITAK ULAKBIM, High Performance and Grid Computing Center (TR-Grid e-Infrastructure) for the calculations reported in the theoretical part of this paper.
dc.identifier.doi10.1039/c3dt52957f
dc.identifier.endpage3433
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.issue9
dc.identifier.pmid24452362
dc.identifier.scopus2-s2.0-84894223357
dc.identifier.scopusqualityQ2
dc.identifier.startpage3428
dc.identifier.urihttps://doi.org/10.1039/c3dt52957f
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24235
dc.identifier.volume43
dc.identifier.wosWOS:000331229200005
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofDalton Transactions
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectLight-Emitting-Diodes
dc.subjectEfficient Blue
dc.subjectAb-Initio
dc.subjectPi
dc.subjectFluorescent
dc.subjectPolymers
dc.subjectAggregation
dc.subjectNaphthalene
dc.subjectComponent
dc.subjectEmission
dc.titleIntramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation
dc.typeArticle

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