Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation
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Tarih
2014
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Soc Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A hexakis(pyrenyloxy) cyclotriphosphazene is synthesized by the reaction of N3P3Cl6 with 2-hydroxypyrene, and its excimer emission through intramolecular interactions in solution and in the solid state has been investigated by fluorescence spectroscopy and X-ray crystallography. Thermal and electrochemical properties were investigated. A DFT benchmark study has been performed to evaluate the intramolecular interactions and molecular orbital levels by comparing with the experimental results.
Açıklama
Anahtar Kelimeler
Light-Emitting-Diodes, Efficient Blue, Ab-Initio, Pi, Fluorescent, Polymers, Aggregation, Naphthalene, Component, Emission
Kaynak
Dalton Transactions
WoS Q Değeri
Q1
Scopus Q Değeri
Q2
Cilt
43
Sayı
9
