Fabrication of Zr MOF-doped polyvinylidene fluoride membranes and testing in H-type microbial fuel cell

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dc.authorid0000-0003-0509-8425en_US
dc.authorid-en_US
dc.authorscopusid55255229000en_US
dc.authorscopusid58773397500en_US
dc.authorwosidF-6352-2018en_US
dc.authorwosid-en_US
dc.contributor.authorUğur Nigiz, Filiz
dc.contributor.authorAkel, Mustafa
dc.date.accessioned2024-02-21T06:26:10Z
dc.date.available2024-02-21T06:26:10Z
dc.date.issued2024en_US
dc.departmentFakülteler, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü
dc.description.abstractMicrobial fuel cells (MFCs) are an important tool that generates electricity from waste biomass. Polymer electron membrane supported dual-chamber MFCs are one of the most tested microbial fuel cells. The most important factor affecting performance in this system is the proton transfer capability of the membrane. In this study, zirconia based metal organic frameworks (Zr-MOF) doped porous membranes were produced, characterized and used in dual chamber (H-type) MFC to generate electricity from animal manure (Cow manure). The effects of MOF ratio on membrane's physical, chemical properties, and on the cell performance were investigated. The incorporation of MOF into the PVDF matrix improved the water retention property of the membrane. The Zr-MOF addition increased the mechanical strength from 0.55 MPa to 1.52 MPa. The cation exchange capacity increased from 1.04 mmol/g to 2.41 mmol/g. It significantly increased the cell electricity production from 0.186V to 0.49V. The power density values are obtained as 5.02 and 13.8 mW/m2 with the pristine and Zr-MOF(4)-PVDF membranes, respectively.en_US
dc.identifier.citationUğur Nigiz, F., Akel, M. (2024) Fabrication of Zr MOF-doped polyvinylidene fluoride membranes and testing in H-type microbial fuel cell. International Journal of Hydrogen Energy, 54, 1264-1272. doi: 10.1016/j.ijhydene.2023.12.094en_US
dc.identifier.doi10.1016/j.ijhydene.2023.12.094
dc.identifier.endpage1272en_US
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.scopus2-s2.0-85180267559
dc.identifier.startpage1264en_US
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2023.12.094
dc.identifier.urihttps://hdl.handle.net/20.500.12428/5713
dc.identifier.volume54en_US
dc.identifier.wosWOS:001142497900001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorUğur Nigiz, Filiz
dc.institutionauthorAkel, Mustafa
dc.language.isoen
dc.publisherElsevier Ltden_US
dc.relation.ispartofInternational Journal of Hydrogen Energyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectElectric productionen_US
dc.subjectMicrobial fuel cellsen_US
dc.subjectZr-metal organic frameworken_US
dc.titleFabrication of Zr MOF-doped polyvinylidene fluoride membranes and testing in H-type microbial fuel cell
dc.typeArticle

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