Catalytic Oxidation of 2,7-Dihydroxynaphthalene

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorBilici, Ali
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:23:07Z
dc.date.available2025-01-27T20:23:07Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractTwo polymer-metal complexes were used for catalytic oxidative polymerization of 2,7-dihydroxynaphthalene (DHN) with the aim of exploiting new and potent catalysts. The structure of the resulting poly(2,7-dihydroxynaphthalene) (PDHN) was confirmed by various spectral techniques: UV-vis, FT-IR, H-1 NMR, C-13 NMR, H-1-H-1 COSY, and H-1-C-13 HSQC. The 3 and 6 positions of the DHN ring were suggested as main coupling sites. The effect of the reaction conditions on the monomer conversions and the polymer molecular weight was determined: yields in the range 74-99% and number-average molecular weights in the range 1700-83 000 g mol(-1) were obtained. Thermal, optical, and electrochemical behaviors of the polymer were also studied. From fluorescence analyses, a case of negative solvatochromism for PDHN was established.
dc.description.sponsorshipCanakkale Onsekiz Mart University Research Fund [2009/39]
dc.description.sponsorshipThe authors thank the Canakkale Onsekiz Mart University Research Fund for financial support (Project No. 2009/39).
dc.identifier.doi10.1021/ie401735j
dc.identifier.endpage109
dc.identifier.issn0888-5885
dc.identifier.issue1
dc.identifier.scopus2-s2.0-84892150037
dc.identifier.scopusqualityQ1
dc.identifier.startpage104
dc.identifier.urihttps://doi.org/10.1021/ie401735j
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22127
dc.identifier.volume53
dc.identifier.wosWOS:000329586100012
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofIndustrial & Engineering Chemistry Research
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCoupling Polymerization
dc.subjectSoluble Polyphenol
dc.subjectEnzymatic Polymerization
dc.subjectCopper(Ii) Complexes
dc.subjectPhenol Derivatives
dc.subjectPolymers
dc.subjectBase
dc.subjectSolvents
dc.subjectWater
dc.titleCatalytic Oxidation of 2,7-Dihydroxynaphthalene
dc.typeArticle

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