Fluorene-based donor-acceptor-type multifunctional polymer with bicarbazole pendant moiety for optoelectronic applications

dc.authorid0000-0003-0238-0169en_US
dc.authorid0000-0001-8352-8326en_US
dc.authorscopusid57219913949en_US
dc.authorscopusid7801633542en_US
dc.authorwosid-en_US
dc.authorwosidAAN-2681-2021en_US
dc.contributor.authorPıravadılı, Selin
dc.contributor.authorDoyranlı, Ceylan
dc.contributor.authorAltınışık, Sinem
dc.contributor.authorBilgili, Hakan
dc.contributor.authorCanımkurbey, Betül
dc.contributor.authorKoyuncu, Sermet
dc.date.accessioned2024-12-11T06:15:02Z
dc.date.available2024-12-11T06:15:02Z
dc.date.issued2021en_US
dc.departmentFakülteler, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü
dc.description.abstractSince limited examples are in the literature in which both organic light-emitting diodes (OLEDs) and electrochromic (EC) applications were performed using the same conjugated polymer, we presented comprehensive EC and electroluminescence (EL) studies of fluorene-based electroactive polymer (e.g., CFP6) consisting of a bicarbazole pendant moiety with quinoxaline as an acceptor bridge. CFP6 was synthesized by a Suzuki cross-coupling polymerization reaction and utilized as an active and emissive layers of the electrochromic device (ECD) and OLED, respectively, due to its high photoluminescence quantum yield intensity and fine thin film forming capability. The optical, electrochemical, cyclic voltammetry measurements, and density functional theory calculations were realized. Electrochemical cross-linking process was applied over the electroactive carbazole subunit of the CFP6 polymer. After the crosslinking process, EC performance was greatly improved. On the other hand, light emission and EL characteristics of OLEDs based on CFP6 emissive layer were realized in detail with six different device architectures to understand light output profile behavior. As a result, CFP6 emitted bright greenish yellow emission with a maximum brightness of 1777 cd/m2 at 215 mA/cm2 in the indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)/CFP6:%10 4,4′-bis(N-carbazolyl)-1,1′-biphenyl (CBP)/Alq3/LiF/Al device architecture.en_US
dc.identifier.citationPıravadılı, S., Doyranlı, C., Altınışık, S., Bilgili, H., Canımkurbey, B., & Koyuncu, S. (2021). Fluorene‐based donor‐acceptor‐type multifunctional polymer with bicarbazole pendant moiety for optoelectronic applications. Journal of Polymer Science, 59(16), 1829–1840. https://doi.org/10.1002/pol.20210221en_US
dc.identifier.doi10.1002/pol.20210221
dc.identifier.endpage1840en_US
dc.identifier.issn2642-4150
dc.identifier.issn2642-4169
dc.identifier.issue16en_US
dc.identifier.scopus2-s2.0-85108316618
dc.identifier.startpage1829en_US
dc.identifier.urihttps://doi.org/10.1002/pol.20210221
dc.identifier.urihttps://hdl.handle.net/20.500.12428/6728
dc.identifier.volume59en_US
dc.identifier.wosWOS:000664469200001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAltınışık, Sinem
dc.institutionauthorKoyuncu, Sermet
dc.language.isoen
dc.publisherJohn Wiley and Sons Incen_US
dc.relation.ispartofJournal of Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.relation.tubitakinfo:eu-repo/grantAgreement/TUBITAK/SOBAG/110T830
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCarbazoleen_US
dc.subjectDonor–acceptor polymeren_US
dc.subjectElectrochromic materials organic light-emitting diodes (OLEDs)en_US
dc.subjectFluoreneen_US
dc.titleFluorene-based donor-acceptor-type multifunctional polymer with bicarbazole pendant moiety for optoelectronic applications
dc.typeArticle

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