Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety

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dc.authorid0000-0001-7330-6076en_US
dc.authorid0000-0002-0764-1965en_US
dc.authorscopusid57189660697en_US
dc.authorscopusid13805114500en_US
dc.authorwosid-en_US
dc.authorwosidH-4339-2013en_US
dc.contributor.authorDayan, Serkan
dc.contributor.authorTercan, Melek
dc.contributor.authorÖzdemir, Fethi Ahmet
dc.contributor.authorAykutoğlu, Gürkan
dc.contributor.authorÖzdemir, Namık
dc.contributor.authorŞerbetçi, Zafer
dc.contributor.authorDinçer, Muharrem
dc.contributor.authorDayan, Osman
dc.date.accessioned2023-04-06T07:32:17Z
dc.date.available2023-04-06T07:32:17Z
dc.date.issued2021en_US
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümü
dc.description.abstractThe palladium(II) complexes PdL1-3, bearing bi-dentated Schiff base ligands (L1-3) were synthesized and characterized by FT-IR, NMR and single crystal-XRD techniques, and the structural, spectroscopic and electronic properties were obtained using the B3LYP density functional method (DFT). The fabricated complexes were used as catalysts in the reduction of some organic pollutants (4-nitrophenol (4-NP), Rhodamine B (Rh B) and methylene blue (MB)) in water at an ambient temperature. The PdL3 complex was recorded as the best catalyst compared to the other complexes and the highest conversion rates were in the order of MB > RhB > 4-NP. Also, the antimicrobial and antifungal activities of all the compounds (ligands and complexes) and the cytotoxic effects on DU-145 and SH-SY5Y cells were investigated. The PdL1-3 complexes show cytotoxic effects, especially against the SH-SY5Y cells. All the synthesized com- pounds showed moderate antimicrobial and antifungal properties.en_US
dc.identifier.citationDayan, S., Tercan, M., Özdemir, F. A., Aykutoğlu, G., Özdemir, N., Şerbetçi, Z., . . . Dayan, O. (2021). Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety. Polyhedron, 199 doi:10.1016/j.poly.2021.115106en_US
dc.identifier.doi10.1016/j.poly.2021.115106
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85102046541
dc.identifier.urihttps://doi.org/10.1016/j.poly.2021.115106
dc.identifier.urihttps://hdl.handle.net/20.500.12428/3939
dc.identifier.volume199en_US
dc.identifier.wosWOS:000632175200001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorTercan, Melek
dc.institutionauthorDayan, Osman
dc.language.isoen
dc.publisherElsevieren_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladium complexesen_US
dc.subjectSchiff baseen_US
dc.subjectDFTen_US
dc.subjectCatalyticen_US
dc.subjectAntibacterialen_US
dc.subjectAntifungalen_US
dc.subjectCytotoxicityen_US
dc.titleCatalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety
dc.typeArticle

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