Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety
Yükleniyor...
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The palladium(II) complexes PdL1-3, bearing bi-dentated Schiff base ligands (L1-3) were synthesized and
characterized by FT-IR, NMR and single crystal-XRD techniques, and the structural, spectroscopic and
electronic properties were obtained using the B3LYP density functional method (DFT). The fabricated
complexes were used as catalysts in the reduction of some organic pollutants (4-nitrophenol (4-NP),
Rhodamine B (Rh B) and methylene blue (MB)) in water at an ambient temperature. The PdL3 complex
was recorded as the best catalyst compared to the other complexes and the highest conversion rates were
in the order of MB > RhB > 4-NP. Also, the antimicrobial and antifungal activities of all the compounds
(ligands and complexes) and the cytotoxic effects on DU-145 and SH-SY5Y cells were investigated. The
PdL1-3 complexes show cytotoxic effects, especially against the SH-SY5Y cells. All the synthesized com-
pounds showed moderate antimicrobial and antifungal properties.
Açıklama
Anahtar Kelimeler
Palladium complexes, Schiff base, DFT, Catalytic, Antibacterial, Antifungal, Cytotoxicity
Kaynak
Polyhedron
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
199
Sayı
Künye
Dayan, S., Tercan, M., Özdemir, F. A., Aykutoğlu, G., Özdemir, N., Şerbetçi, Z., . . . Dayan, O. (2021). Catalytic and biological activities of homoleptic palladium(II) complexes bearing the 2-aminobenzothiazole moiety. Polyhedron, 199 doi:10.1016/j.poly.2021.115106
