Influence of the enzymatic and the chemical oxidative polymerization of trifluoromethyl-substituted aromatic diamine on thermal and photophysical properties

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dc.authorid0000-0002-0361-7458en_US
dc.authorid0000-0002-2004-8859en_US
dc.authorid0000-0002-9813-2962en_US
dc.authorid0000-0002-1192-9726en_US
dc.authorscopusid23502381000en_US
dc.authorscopusid55959291700en_US
dc.authorscopusid56250747600en_US
dc.authorscopusid55336531500en_US
dc.authorwosidAAE-6795-2019en_US
dc.authorwosid-en_US
dc.authorwosidABD-2324-2020en_US
dc.authorwosid-en_US
dc.contributor.authorSöyüt, Hakan
dc.contributor.authorKolcu, Feyza
dc.contributor.authorKaya, İsmet
dc.contributor.authorYaşar, Alper Ömer
dc.date.accessioned2023-08-21T08:32:04Z
dc.date.available2023-08-21T08:32:04Z
dc.date.issued2023en_US
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümü
dc.departmentMeslek Yüksekokulları, Lapseki Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümü
dc.description.abstractSemi-conductive polymers have been used in a few area applications such as coatings, accumulators, solar cells, rechargeable batteries, ion sensors, photoreceptors, light-emitting diodes and electrochromic instruments. Poly(4-(trifluoromethyl)benzene-1,2-diamine)s of Poly(TFMBDA)-O and Poly(TFMBDA)-E were synthesized via chemical oxidative and enzymatic polymerization methods, respectively, using 4-(trifluoromethyl)benzene-1,2-diamine (TFMBDA) as monomer. FT-IR, UV–vis and 1H-NMR and 13C-NMR instruments were utilized in order to confirm the structures of all compounds. The Mw values of the polymers and their PDI values were found to be between 5000–7000 Da and 1.045–1.115, respectively, from GPC measurements. The glass temperature of phenazine-type structure of Poly(TFMBDA)-O was higher compared to that of Poly(TFMBDA)-E, which was composed of phenyl units linked with –NH bridges. As soon as Poly(TFMBDA)-O and Poly(TFMBDA)-E were excited by UV light, they had a quantum efficiency of 6.3% and 13.7%, respectively, in DMF for violet photoluminescence (PL) emission depending on photoluminescence measurement. SEM images revealed that Poly(TFMBDA)-O consisted of approximately 1–2 μm of uniform micro-spheres and a granular surface with different pore diameters. The enzymatic oxidation with HRP afforded Poly(TFMBDA)-E micro-rods of about 5–10 μm-long shape in their SEM images.en_US
dc.identifier.citationSöyüt, H., Kolcu, F., İsmet, Kaya, & Yaşar, A. Ö. (2023). Influence of the enzymatic and the chemical oxidative polymerization of trifluoromethyl‐substituted aromatic diamine on thermal and photophysical properties. Polymers for Advanced Technologies, 34(4), 1293–1306. https://doi.org/10.1002/pat.5970en_US
dc.identifier.doi10.1002/pat.5970
dc.identifier.endpage1306en_US
dc.identifier.issn1042-7147
dc.identifier.issn1099-1581
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85145455408
dc.identifier.startpage1293en_US
dc.identifier.urihttps://doi.org/10.1002/pat.5970
dc.identifier.urihttps://hdl.handle.net/20.500.12428/4513
dc.identifier.volume34en_US
dc.identifier.wosWOS:000906788700001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorSöyüt, Hakan
dc.institutionauthorKolcu, Feyza
dc.institutionauthorKaya, İsmet
dc.institutionauthorYaşar, Alper Ömer
dc.language.isoen
dc.publisherJohn Wiley and Sons Ltden_US
dc.relation.ispartofPolymers for Advanced Technologiesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject4-(trifluoromethyl)benzene-1,2-diamine)en_US
dc.subjectChemical oxidative polymerizationen_US
dc.subjectEnzymatic polymerizationen_US
dc.subjectFluorescenceen_US
dc.titleInfluence of the enzymatic and the chemical oxidative polymerization of trifluoromethyl-substituted aromatic diamine on thermal and photophysical properties
dc.typeArticle

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