Facile synthesis of self-stabilized polyphenol nanoparticles

Basit Öğe Kaydı
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridBilici, Ali / 0000-0002-1377-5580
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.authoridYıldırım, Mehmet / 0000-0001-9948-9106
dc.contributor.authorBilici, Ali
dc.contributor.authorDoğan, Fatih
dc.contributor.authorYıldırım, Mehmet
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:29:08Z
dc.date.available2025-01-27T20:29:08Z
dc.date.issued2013
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractWe describe here the facile synthesis (in two-steps) of green light emitting phenol polymer with an azomethine side group. For this purpose, hydroxy functionalized-Schiff base monomer, HPMBT, was obtained by condensation of 2,3,4-trihydroxybenzaldehyde with 2-aminophenol. Subsequent oxidation of the monomer in alkaline medium by NaOCl yielded to corresponding phenol polymer (PHPMBT) with molecular weight ca. 34,500 Da. The characterizations were performed by NMR, FT-IR, UV-vis, gel permeation chromatography (GPC), thermogravimetry (TG), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), cyclic voltammetry (CV), photoluminescence (PL), dynamic light scattering (DLS) and scanning electron microscope (SEM) analysis. PL analysis indicated that HPMBT was non-fluorescent whereas PHPMBT was a green light emitter. In addition, the redox behaviors of the polymer were explored by cyclic voltammetry (CV), assigned it's electroactive nature. The formation of nano-sized polyphenol particles was revealed by the SEM and DLS analyses. A possible mechanism for the formation and self-stabilization of the polyphenol nanoparticles was also suggested. (C) 2013 Elsevier B.V. All rights reserved.
dc.description.sponsorshipCanakkale Onsekiz Mart University Research Fund; project (COMU) [2010/118]
dc.description.sponsorshipDr. Fatih Dogan thanks to Canakkale Onsekiz Mart University Research Fund for support with the project (COMU Project No: 2010/118).
dc.identifier.doi10.1016/j.matchemphys.2013.02.066
dc.identifier.endpage74
dc.identifier.issn0254-0584
dc.identifier.issn1879-3312
dc.identifier.issue1
dc.identifier.scopus2-s2.0-84877582272
dc.identifier.scopusqualityQ1
dc.identifier.startpage66
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2013.02.066
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22836
dc.identifier.volume140
dc.identifier.wosWOS:000319789500011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofMaterials Chemistry and Physics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPolymers
dc.subjectElectrochemical techniques
dc.subjectPhotoluminescence spectroscopy
dc.subjectNuclear magnetic resonance
dc.titleFacile synthesis of self-stabilized polyphenol nanoparticles
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Ali Bilici_Makale.pdf
Boyut:
1.63 MB
Biçim:
Adobe Portable Document Format
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Koleksiyonu
Lapseki Meslek Yüksekokulu Koleksiyonu
Matematik ve Fen Bilimleri Eğitimi Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu