Hydrogel-Biochar composites for effective organic contaminant removal from aqueous media

dc.authoridKasımoğlu, Murat / 0000-0002-7407-5991
dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridYılmaz, Selahattin / 0000-0003-4607-3523
dc.contributor.authorKarakoyun, Necdet
dc.contributor.authorKubilay, Şenol
dc.contributor.authorAktaş, Nahit
dc.contributor.authorTurhan, Ömer
dc.contributor.authorKasımoğlu, Murat
dc.contributor.authorYılmaz, Selahattin
dc.contributor.authorŞahiner, Nurettin
dc.date.accessioned2025-01-27T20:50:29Z
dc.date.available2025-01-27T20:50:29Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this study, p(acrylamide)-chicken biochar (p(AAm)-CB), p(acrylamide)-wood biochar (p(AAm)-WB), and p(acrylamide)-tire biochar (p(AAm)-TB) hydrogel composites were prepared using acrylamide (AAm) as monomer with the corresponding biochars, with N,N'-methylenebisacrylamide (MBA) as crosslinker and ammonium persulfate (APS) as initiator. P(AAm)-CB, p(AAm)-WB, and p(AAm)-TB were used as adsorbents to remove phenol from aqueous environments. The synthesized p(AAm)-CB, p(AAm)-WB, p(AAm)-TB and p(AAm) hydrogel composites had swelling values of 1112, 1045, 847, and 623%, respectively in distilled water. The prepared hydrogel biochar material compositions were examined using an elemental analyzer. Absorption of phenol into p(AAm)-WB was studied at different pHs to determine the optimum pH for maximum removal of phenol. The ionic strength of the medium was varied between 0.01 and 1 mol L-1 to determine the effect of salt (NaCl) on the absorption characteristics and it was found that the absorption of phenol increased with a decrease in the amount of salt. Langmuir and Freundlich isotherms were applied to describe the absorption characteristics and the Langmuir isotherm describes the absorption phenomena in this study much better than the Freundlich isotherm. Pseudo-first-order and pseudo-second-order kinetic studies were also applied to determine absorption characteristic. (C) 2011 Elsevier B.V. All rights reserved.
dc.description.sponsorshipTurkish Academy of Science; COMU [2011/1]
dc.description.sponsorshipN. Sahiner is grateful to the Turkish Academy of Science for financial support under the 2008 TUBA-GEBIP program. This work is also supported by COMU (2011/1).
dc.identifier.doi10.1016/j.desal.2011.07.014
dc.identifier.endpage325
dc.identifier.issn0011-9164
dc.identifier.issn1873-4464
dc.identifier.issue1-3
dc.identifier.scopus2-s2.0-80053305840
dc.identifier.scopusqualityQ1
dc.identifier.startpage319
dc.identifier.urihttps://doi.org/10.1016/j.desal.2011.07.014
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25504
dc.identifier.volume280
dc.identifier.wosWOS:000296365800043
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofDesalination
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHydrogel
dc.subjectBiochar
dc.subjectHydrogel-composite
dc.subjectPhenol absorption
dc.subjectOrganic contaminant removal
dc.titleHydrogel-Biochar composites for effective organic contaminant removal from aqueous media
dc.typeArticle

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