Thiophene substituted phenothiazine polymers: Design, synthesis and characterization

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorTezel, Ruhiye Nilay
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:17:14Z
dc.date.available2025-01-27T20:17:14Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractIn this paper, the polymers containing phenothiazine were synthesized via oxidative polymerization reaction by FeCl3 as oxidant. These polymers contain ether unit, aliphatic chain and aromatic groups as bridges in their structures. The effects of the groups on the optical, thermal, morphological properties of the polymers were investigated. The physical and chemical properties of the monomers and the polymers were identified by FT-IR, NMR, UV-Vis, thermogravimetry (TG), cyclic voltammetry (CV), fluorescence analysis. According to the fluorescence analyses, polymer containing aliphatic ether bridge emitted yellow colour based on the turning of excitation wavelength. The yellow solution of polymer containing aliphatic ether bridge turned into turquoise when excited with the wavelength of 365 nm. Thermal analyses demonstrated that polymer containing phenyl bridge compound had 38% residue amount. Due to fluorescent and thermal properties, these polymers could be used in various applications such as spectrofluorometric ion sensor and polymeric light emitting diodes (PLEDs) with yellow and turquoise emissions. (C) 2018 Production and hosting by Elsevier B.V. on behalf of King Saud University.
dc.description.sponsorshipGovernment Planning Organization [GPO2010K120710]
dc.description.sponsorshipThe authors would like to thank Government Planning Organization for the financial support (Project No. GPO2010K120710).
dc.identifier.doi10.1016/j.arabjc.2018.09.004
dc.identifier.endpage3136
dc.identifier.issn1878-5352
dc.identifier.issn1878-5379
dc.identifier.issue1
dc.identifier.scopus2-s2.0-85054171310
dc.identifier.scopusqualityQ1
dc.identifier.startpage3123
dc.identifier.urihttps://doi.org/10.1016/j.arabjc.2018.09.004
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21525
dc.identifier.volume13
dc.identifier.wosWOS:000505076000244
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofArabian Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectPhenothiazine
dc.subjectOxidative polymerization
dc.subjectFluorescence
dc.subjectThermal analysis
dc.subjectSEM
dc.titleThiophene substituted phenothiazine polymers: Design, synthesis and characterization
dc.typeArticle

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