Electrochemical Measurements of the In(III) Ions Electroreduction; the Influence of Mixed Adsorption Layers ACT-CTAB and ACT-SDS
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Tarih
2024
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Electrochemical Soc Inc
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Using voltammetric and impedance methods, the effects of mixed adsorption layers ACT-CTAB and ACT-SDS on the kinetics and mechanism of In(III) ions electroreduction were investigated. Acetazolamide (ACT) was shown to catalyse the course of the electrode reaction (according to the cap-pair rule). The multi-step nature of the In(III) ions electroreduction process in each of the systems studied in the chemical step of formation of the active In(III) - ACT complexes in the adsorption layer playing an important role is demonstrated. The presence of the cationic surfactant CTAB increases the dynamics of acceleration of the In(III) ion electroreduction process by ACT, while the presence of the anionic surfactant SDS inhibits this reaction.
Açıklama
Anahtar Kelimeler
electroanalytical electrochemistry, electrocatalysis, electrode kinetics
Kaynak
Journal of The Electrochemical Society
WoS Q Değeri
N/A
Scopus Q Değeri
Q1
Cilt
171
Sayı
7
