Preparation and crystal structure of binuclear chloro{6-[[chloro(triphenylphosphine)platinum](mesitylimino)methyl]pyridin-2-yl}bis(triphenylphosphine)platinum(II)

Basit Öğe Kaydı
dc.authoridAygun, Muhittin/0000-0001-9670-9062
dc.authoridGokce, Aytac Gurhan/0000-0003-0083-7452
dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridGunay, Muhammet Emin/0000-0003-3855-9531
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.contributor.authorGunay, M. Emin
dc.contributor.authorDayan, Osman
dc.contributor.authorGokce, Aytac Gurhan
dc.contributor.authorAygun, Muhittin
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-01-27T20:22:32Z
dc.date.available2025-01-27T20:22:32Z
dc.date.issued2008
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractTreatment of N,N'-bis(mesityl)pyridine-2,6-carboxyimidoyldichloride, 1, in toluene solution with [Pt(PPh3)(4)] at 100 degrees C afforded a novel platinacyclic compound, 3, in 63% yield, instead of the expected compound 2. The molecular and crystal structures of the title compound, 3, have been determined by the single crystal X-ray diffraction technique. The coordination geometries around the Pt atoms are distorted square-planar. In the crystal structure, the molecules are linked by a pair of C-H center dot center dot center dot N hydrogen bonds into a centrosymmetric dinner with an R-2(2) (16) ring, centred at (1/2,1/2,1/2). (C) 2008 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipFaculty of Arts and Sciences, Ondokuz Mayis University, Turkey [F279]; Dokuz Eylul University [04.KB.FEN.100]
dc.description.sponsorshipThe authors acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased under Grant No. F279 of the University Research Fund) and Dokuz Eylul University Research Funds (Project No.: 04.KB.FEN.100).
dc.identifier.doi10.1016/j.poly.2008.09.019
dc.identifier.endpage3610
dc.identifier.issn0277-5387
dc.identifier.issue18
dc.identifier.scopus2-s2.0-56349151806
dc.identifier.scopusqualityQ2
dc.identifier.startpage3607
dc.identifier.urihttps://doi.org/10.1016/j.poly.2008.09.019
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21936
dc.identifier.volume27
dc.identifier.wosWOS:000261912300011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectBinuclear platinum complex
dc.subjectPlatinalactam
dc.subjectCentrosymmetric dimer
dc.subjectImidoyl chlorides
dc.titlePreparation and crystal structure of binuclear chloro{6-[[chloro(triphenylphosphine)platinum](mesitylimino)methyl]pyridin-2-yl}bis(triphenylphosphine)platinum(II)
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu