Preparation and crystal structure of binuclear chloro{6-[[chloro(triphenylphosphine)platinum](mesitylimino)methyl]pyridin-2-yl}bis(triphenylphosphine)platinum(II)
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Tarih
2008
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Treatment of N,N'-bis(mesityl)pyridine-2,6-carboxyimidoyldichloride, 1, in toluene solution with [Pt(PPh3)(4)] at 100 degrees C afforded a novel platinacyclic compound, 3, in 63% yield, instead of the expected compound 2. The molecular and crystal structures of the title compound, 3, have been determined by the single crystal X-ray diffraction technique. The coordination geometries around the Pt atoms are distorted square-planar. In the crystal structure, the molecules are linked by a pair of C-H center dot center dot center dot N hydrogen bonds into a centrosymmetric dinner with an R-2(2) (16) ring, centred at (1/2,1/2,1/2). (C) 2008 Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Binuclear platinum complex, Platinalactam, Centrosymmetric dimer, Imidoyl chlorides
Kaynak
Polyhedron
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
27
Sayı
18
