Integrated waste reduction by production of bio-magnetic adsorbents via copyrolysis of waste red mud and residual sugar beet pulp: Target zero waste

dc.authoridArslanoğlu, Hasan / 0000-0002-3132-4468
dc.contributor.authorSağlam, Semanur
dc.contributor.authorTürk, Feride N.
dc.contributor.authorArslanoğlu, Hasan
dc.date.accessioned2025-05-29T02:57:59Z
dc.date.available2025-05-29T02:57:59Z
dc.date.issued2025
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractRed mud, a waste of the aluminum plant, is the result of calcination of bauxite ore with sodium hydroxide at high temperature and concentration. This waste, which is the fearful dream of alumina production factories, attracts attention with its rich iron content. In this study, magnetic activated carbon (MAC) was obtained from the co- pyrolysis of sugar beet pulp and red sludge. The removal of basic yellow basic yellow 5 GL (BY5GL) dyestuff from aqueous solutions was investigated with the obtained MAC. MAC was characterized by X-ray diffraction, FTIR, SEM-EDX, DSC, VSM and BET surface area. VSM analysis revealed a magnetism of 46.11 emu/g. RSM Taguchi statistical analysis was utilized. According to the L16 orthogonal array consisting of 4 factors and 4 levels, the optimum MAC was obtained at 800 degrees C, 120 min, 5 impregnation and 0.5 biomass/K2CO3 ratio. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm equations were applied. Pseudo-first, pseudo- second and intra-particle diffusion kinetic models were analyzed. Langmuir adsorption isotherm and pseudo- second kinetic model gave the best results. It was observed that pH was the most effective parameter for BY5GL adsorption. The maximum adsorption capacity was found to be 175.4 mg.g-1 at pH 7, 20 degrees C, 360 min contact time, 5 g.L-1 adsorbent dosage and 50 mg.L-1 dyestuff concentration. Activation energy and thermodynamic parameters of the adsorbent were also investigated for dyestuff adsorption.
dc.description.sponsorshipCOMU Scientific Research Projects Commission [FBA-2023-4480]
dc.description.sponsorshipThis study was supported by the COMU Scientific Research Projects Commission with the project numbered FBA-2023-4480.
dc.identifier.doi10.1016/j.jenvman.2025.124807
dc.identifier.issn0301-4797
dc.identifier.issn1095-8630
dc.identifier.pmid40068339
dc.identifier.scopus2-s2.0-86000443765
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jenvman.2025.124807
dc.identifier.urihttps://hdl.handle.net/20.500.12428/30224
dc.identifier.volume380
dc.identifier.wosWOS:001446721500001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAcademic Press Ltd- Elsevier Science Ltd
dc.relation.ispartofJournal of Environmental Management
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250529
dc.subjectRed mud
dc.subjectMagnetic activated carbon
dc.subjectActivated carbon
dc.subjectBasic yellow 5 GL
dc.titleIntegrated waste reduction by production of bio-magnetic adsorbents via copyrolysis of waste red mud and residual sugar beet pulp: Target zero waste
dc.typeArticle

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