Spectroscopic study, antimicrobial activity and crystal structures of N-(2-hydroxy-5-nitrobenzalidene)4-aminomorpholine and N-(2-hydroxy-1-naphthylidene)4-aminomorpholine

Basit Öğe Kaydı
dc.authoridDülger, Başaran / 0000-0002-3184-2652
dc.authoridYıldız, Mustafa / 0000-0001-5833-7499
dc.authoridErdener, Diğdem / 0000-0002-4226-0455
dc.contributor.authorYıldız, Mustafa
dc.contributor.authorÜnver, H.
dc.contributor.authorDülger, Başaran
dc.contributor.authorErdener, Diğdem
dc.contributor.authorOcak, N.
dc.contributor.authorErdönmez, A.
dc.contributor.authorDurlu, Tahsin Nuri
dc.date.accessioned2025-01-27T20:56:24Z
dc.date.available2025-01-27T20:56:24Z
dc.date.issued2005
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractSchiff bases N-(2-hydroxy-3-nitrobenzalidene)4-aminomorpholine (1) and N-(2-hydroxy- I -naphthylidene)4-aminomorpholine (2) were synthesized from the reaction of 4-aminomorpholine with 2-hydroxy-5-nitrobenzaldehyde and 2-hydroxy- 1 -naphthaldehyde. Compounds 1 and 2 were characterized by elemental analysis, IR, H-1 NMR, C-13 NMR and UV-Visible techniques. The UV-Visible spectra of the Schiff bases with OH group in ortho position to the imino group were studied in polar and nonpolar solvents in acidic and basic media. The structures of compounds 1 and 2 have been examined cyrstallographically, for two compounds exist as dominant form of enol-imines in both the solutions and solid state. The title compounds 1 and 2 crystallize in the monoclinic space group P2(1)/c and P2(1)/n with unit cell parameters: a=8.410(1) and 11.911(3), b=6.350(9) and 4.860(9), c=21.728(3) and 22.381(6) angstrom, beta=90.190(1) and 95.6(2)degrees, V=1160.6(3) and 1289.5(5) angstrom(3), D-x = 1.438 and 1.320 g cm(-3), respectively. The crystal structures were solved by direct methods and refined by full-matrix least squares. The antimicrobial activities of compounds 1 and 2 have also been studied. The antimicrobial activities of the ligands have been screened in vitro against the organisms Escherichia coli ATCC 11230, Staphylococcus aureus ATCC 6538, Klebsiella pneumoniae UC57, Micrococcus luteus La 297 1, Proteus vulgaris ATCC 8427, Pseudomonas aeruginosa ATCC 27853, Mycobacterium smegmatis CCM 2067, Bacillus cereus ATCC 7064, Listeria monocytogenes ATCC 15313, Candida albicans ATCC 1023 1, Kluyveromyces fragilis NRRL 2415, Rhodotorula rubra DSM 70403, Debaryomyces hansenii DSM 70238 and Hanseniaspora guilliennondii DSM 3432. 0 2004 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2004.10.029
dc.identifier.endpage260
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.issue1-3
dc.identifier.scopus2-s2.0-14644414194
dc.identifier.scopusqualityQ1
dc.identifier.startpage253
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2004.10.029
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26392
dc.identifier.volume738
dc.identifier.wosWOS:000227744500037
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSchiff base
dc.subjectspectroscopic studies
dc.subjectcrystal structure
dc.subjectmorpholine
dc.subjectbiological activities
dc.titleSpectroscopic study, antimicrobial activity and crystal structures of N-(2-hydroxy-5-nitrobenzalidene)4-aminomorpholine and N-(2-hydroxy-1-naphthylidene)4-aminomorpholine
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Mustafa Yildiz_Makale.pdf
Boyut:
321.27 KB
Biçim:
Adobe Portable Document Format
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Biyoloji Bölümü Koleksiyonu
Kimya Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu