A green light emitting polymer in a PMMA matrix: oligo(azomethine-ether) with benzothiazole moieties

dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridYıldırım, Mehmet / 0000-0001-9948-9106
dc.contributor.authorYıldırım, Mehmet
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T21:01:52Z
dc.date.available2025-01-27T21:01:52Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis study aimed to synthesize an oligo(azomethine-ether) with benzothiazole moiety in organic medium by means of chemical oxidative polycondensation (OP). Optical properties were examined by photoluminescence (PL) and UV-Vis measurements both in solutions and solid film involved a poly (methyl methacrylate) (PMMA) matrix. Oligomer film in the PMMA matrix emitted a fine green light with a fluorescence quantum yield (QY) of 3.30%. Spectral and thermal observations showed a high rate of C-O-C coupling (cross-linking) for the oligomer. SEC results indicated low molecular weight (similar to 3200-4650 g mol(-1)) and the oligomer was soluble in organic solvents with high polarity. Electrochemical behavior was characterized by cyclic voltammetry (CV), morphological properties by scanning electron microscopy (SEM), and thermal characteristics by TG-DTA and DSC techniques.
dc.identifier.doi10.3906/kim-1405-66
dc.identifier.endpage234
dc.identifier.issn1300-0527
dc.identifier.issue2
dc.identifier.scopus2-s2.0-84929579916
dc.identifier.scopusqualityQ3
dc.identifier.startpage217
dc.identifier.trdizinid170956
dc.identifier.urihttps://doi.org/10.3906/kim-1405-66
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/170956
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27217
dc.identifier.volume39
dc.identifier.wosWOS:000353336300002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectPLED
dc.subjectgreen emission
dc.subjectcross-linking
dc.subjectconjugated polymers
dc.subjectoligo(azomethine-ether)
dc.titleA green light emitting polymer in a PMMA matrix: oligo(azomethine-ether) with benzothiazole moieties
dc.typeArticle

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