Synthesis, characterization, thermal and photophysical properties of novel strontium (II) phthalocyanine

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dc.authorid0000-0002-4572-4905en_US
dc.authorscopusid57190122378en_US
dc.authorwosid-en_US
dc.contributor.authorPişkin, Mehmet
dc.date.accessioned2023-06-05T12:22:27Z
dc.date.available2023-06-05T12:22:27Z
dc.date.issued2022en_US
dc.departmentMeslek Yüksekokulları, Çanakkale Teknik Bilimler Meslek Yüksekokulu, Gıda İşleme Bölümü
dc.description.abstractNewly phthalocyanine derivative which carries 2,6-dimethoxyphenoxy bioactive groups as tetrakis from non-peripheral positions of the phthalocyanine ring and contains strontium (II) as an alkaline earth metal ion in its cavity was synthesized. Its structure was characterized by elemental analysis, fourier transform infrared, ultraviolet–visible, proton nuclear magnetic resonance, carbon-13 nuclear magnetic resonance and matrix assisted laser desorption/ionization time-of-flight mass spectroscopic techniques. Its thermal properties were determined using thermogravimetric analysis and differential scanning calorimetry. The solubility and aggregation behavior in polar protic, polar aprotic and non-polar solvents were determined. Also, its aggregation behavior was studied at a range of different concentrations in dimethyl sulfoxide. The photophysical properties (fluorescence quantum yield, fluorescence lifetime, natural radiation lifetime, non-radiative lifetime, rate constant for fluorescence, non-radiative rate constant and observed fluorescence decay rate constant values) of newly strontium(II) phthalocyanine were determined in dimethyl sulfoxide. In addition, the spectroscopic, thermal and photophysical properties of newly strontium(II) phthalocyanine were also compared with its counterparts reported in the literature. The findings of this work can be useful to those systems involving changes in the forms analogous to the compound studied. In addition, newly strontium(II) phthalocyanine with particularly sufficient and enhanced photophysical properties, could be a photosensitizer candidate for photocatalytic applications.en_US
dc.identifier.citationPişkin, M. (2022). Synthesis, characterization, thermal and photophysical properties of novel strontium (II) phthalocyanine. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 102(1-2), 35-44. doi:10.1007/s10847-021-01094-2en_US
dc.identifier.doi10.1007/s10847-021-01094-2
dc.identifier.endpage44en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue1-2en_US
dc.identifier.scopus2-s2.0-85113770813
dc.identifier.startpage35en_US
dc.identifier.urihttps://doi.org/10.1007/s10847-021-01094-2
dc.identifier.urihttps://hdl.handle.net/20.500.12428/4249
dc.identifier.volume102en_US
dc.identifier.wosWOS:000687507000001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorPişkin, Mehmet
dc.language.isoen
dc.publisherSpringer Science and Business Media B.V.en_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhotophysical propertiesen_US
dc.subjectPhthalocyanineen_US
dc.subjectSpectroscopicen_US
dc.subjectStrontium (II)en_US
dc.subjectThermalen_US
dc.titleSynthesis, characterization, thermal and photophysical properties of novel strontium (II) phthalocyanine
dc.typeArticle

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