Electrocatalytic oxidation of sulphide using a pencil graphite electrode modified with hematoxylin

dc.authoridDilgin, Yusuf/0000-0002-2980-6871
dc.authoridGiray Dilgin, Didem/0000-0002-3487-3470
dc.contributor.authorDilgin, Yusuf
dc.contributor.authorKizilkaya, Bayram
dc.contributor.authorErtek, Bensu
dc.contributor.authorIsik, Firat
dc.contributor.authorDilgin, Didem Giray
dc.date.accessioned2025-01-27T20:31:21Z
dc.date.available2025-01-27T20:31:21Z
dc.date.issued2012
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe present study describes a new approach for the investigation of electrocatalytic oxidation of sulphide using a pencil graphite electrode modified with hematoxylin (PGE/HMT). Adsorption procedure was used for the preparation of the modified electrodes. It was observed that PGE/HMT showed a significant electrocatalytic activity toward sulphide oxidation. Cyclic voltammetric studies showed that the peak potential of sulphide shifted from +480 mV at bare PGE to +220 mV at PGE/HMT. The electrocatalytic currents obtained from amperometric measurements at +200 mV versus Ag/AgCl/KClsat and at pH 8.0 BR buffer solution containing 0.1 M KCl were linearly related to the concentration of sulphide. The calibration graph consisted of a linear segment of 1-200 mu M with a detection limit of 0.4 mu M (based on 3s(b)). The proposed method was successfully applied to the determination of sulphide in waste waters and was compared with the spectrophotometric method. (C) 2012 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.snb.2012.03.020
dc.identifier.endpage229
dc.identifier.issn0925-4005
dc.identifier.scopus2-s2.0-84864288657
dc.identifier.scopusqualityQ1
dc.identifier.startpage223
dc.identifier.urihttps://doi.org/10.1016/j.snb.2012.03.020
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23113
dc.identifier.volume171
dc.identifier.wosWOS:000308572700024
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSensors and Actuators B-Chemical
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectElectrocatalytic oxidation
dc.subjectHematoxylin
dc.subjectSulphide
dc.subjectPencil graphite electrode
dc.titleElectrocatalytic oxidation of sulphide using a pencil graphite electrode modified with hematoxylin
dc.typeArticle

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