Characterization and use of (E)-2-[(6-methoxybenzo[d]thiazol-2-ylimino)methyl]phenol as an anion sensor and a DNA-binding agent

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dc.authoridASLAN, KADIR/0000-0002-7617-0175
dc.authoridUnver, Huseyin/0000-0003-3968-4385
dc.contributor.authorBarare, Belygona
dc.contributor.authorYıldız, Mustafa
dc.contributor.authorUnver, Hyseyin
dc.contributor.authorAslan, Kadir
dc.date.accessioned2025-01-27T20:54:17Z
dc.date.available2025-01-27T20:54:17Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractWe report the spectroscopic characterization, DNA binding, and anion sensor properties, of a Schiff base, that is, (E)-2-[(6-methoxybenzo[d]thiazol-2-ylimino)methyl]phenol from the reaction of 2-hydroxyben-zaldehyde with 2-amino-6-methoxybenzothiazole. Colorimetric measurements revealed that the title compound was sensitive to F-, AcO-, CN-, and OH- anions. Fluorescence measurements demonstrated that the title compound can be used to detect CN-. The interactions between the receptor and anions were confirmed using H-1 NMR titration method. The UV-Vis spectroscopy studies of the interactions between the compound and calf thymus DNA (CT-DNA) revealed intercalative binding of CT-DNA to the title compound. (C) 2015 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (Turkiye Bilimsel ve Teknolojik Arastirma Kurumu) [BIDEB-2221]
dc.description.sponsorshipThe authors are grateful to the Scientific and Technical Research Council of Turkey (Turkiye Bilimsel ve Teknolojik Arastirma Kurumu) for the financial support of this work, grant number BIDEB-2221 (Sabbatical for K.A.).
dc.identifier.doi10.1016/j.tetlet.2015.12.071
dc.identifier.endpage542
dc.identifier.issn0040-4039
dc.identifier.issue5
dc.identifier.scopus2-s2.0-84954404736
dc.identifier.scopusqualityQ3
dc.identifier.startpage537
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2015.12.071
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26034
dc.identifier.volume57
dc.identifier.wosWOS:000369557300008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofTetrahedron Letters
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectSchiff base
dc.subject2-Amino-6-methoxybenzothiazole
dc.subjectSpectroscopy
dc.subjectCalf thymus-DNA
dc.subjectAnion sensors
dc.subjectH-1 NMR titration
dc.titleCharacterization and use of (E)-2-[(6-methoxybenzo[d]thiazol-2-ylimino)methyl]phenol as an anion sensor and a DNA-binding agent
dc.typeArticle

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