Poly(methyl methacrylate)/clay nanocomposites by photoinitiated free radical polymerization using intercalated monomer

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dc.authoridOral, Ayhan/0000-0003-4965-8754
dc.authoridtasdelen, mehmet atilla/0000-0002-1234-3364
dc.authoridtasdelen, mehmet atilla/0000-0002-7012-7029
dc.contributor.authorOral, Ayhan
dc.contributor.authorTasdelen, Mehmet Atilla
dc.contributor.authorDemirel, Adem Levent
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2025-01-27T20:39:05Z
dc.date.available2025-01-27T20:39:05Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA series of poly(methyl methacrylate)/montmorillonite (PMMA/MMT) nanocomposite were prepared by Successfully dispersing the inorganic nanolayers of MMT clay in an organic PMMA matrix via in situ photoinitiated free radical polymerization. Methyl methacrylate monomer was first intercalated into the interlayer regions of organophilic clay hosts by click chemistry followed by a typical photoinitiated free radical polymerization. The intercalated monomer was characterized by FT-IR spectroscopy, elemental analysis and thermogravimetric analysis methods. The intercalation ability of the modified monomer and exfoliated nanocomposite structure were confirmed by X-ray diffraction spectroscopy (XRD), transmission electron microscopy (TEM) and atomic force microscopy (AFM). Thermal stability of PMMA/MMT nanocomposites was also studied by both differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). (c) 2009 Elsevier Ltd. All rights reserved.
dc.identifier.doi10.1016/j.polymer.2009.06.020
dc.identifier.endpage3910
dc.identifier.issn0032-3861
dc.identifier.issn1873-2291
dc.identifier.issue16
dc.identifier.scopus2-s2.0-67650936050
dc.identifier.scopusqualityQ1
dc.identifier.startpage3905
dc.identifier.urihttps://doi.org/10.1016/j.polymer.2009.06.020
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23857
dc.identifier.volume50
dc.identifier.wosWOS:000268732500004
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofPolymer
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectNanocomposites
dc.subjectClick chemistry
dc.subjectPoly(methyl methacrylate)
dc.titlePoly(methyl methacrylate)/clay nanocomposites by photoinitiated free radical polymerization using intercalated monomer
dc.typeArticle

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