The preparation of new palladium (II) complexes with Schiff base type ligands and its impregnated Al2O3materials: As the catalysts for degradation/reduction of organic dyes

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dc.authoriddayan, osman/0000-0002-0764-1965
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.contributor.authorSelvi, Gizem
dc.contributor.authorTercan, Melek
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDayan, Osman
dc.date.accessioned2025-01-27T21:03:37Z
dc.date.available2025-01-27T21:03:37Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe removal of organic dyes used in many sectors such as textile, paper, leather, and packaging from water sources is very important in terms of preventing the spread of industrial pollutants to the environment. Transition metal complexes supported to an inorganic solid material are frequently used for the degradation/reduction of organic dyes causing this pollution. In this study, new Pd (II) complexes with Schiff base ligands were synthesized and structurally characterized by nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FT-IR), mass spectrometry (MS), and single-crystal X-ray diffraction (sc-XRD) spectroscopic methods. Then, the Al2O3-impregnated materials of these Pd (II) complexes were prepared and characterized by scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), FT-IR, and thermogravimetry (TG) techniques. The catalytic activities of the synthesized Pd (II) complexes and their Al2O3-impregnated materials were comparatively analyzed to investigate the degradation/reduction of organic dyes (2-nitroaniline, 4-nitroaniline, 4-nitrophenol, eosin yellow, and methylene blue). The catalytic results indicate that Al2O3-impregnated materials are very active catalysts for the degradation/reduction of organic dyes under those circumstances. Conversions of up to 98% for all substrates were obtained after 5 min at ambient temperature.
dc.description.sponsorshipOndokuz Mayis Universitesi [FEN.1906.19.001]; Ondokuz Mayis University; Scientific Research Project Commissions of Canakkale Onsekiz Mart University [FYL-2019-2883]
dc.description.sponsorshipOndokuz Mayis Universitesi, Grant/Award Number: PYO. FEN.1906.19.001; Ondokuz Mayis University; Scientific Research Project Commissions of Canakkale Onsekiz Mart University, Grant/Award Number: FYL-2019-2883
dc.identifier.doi10.1002/aoc.6009
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue12
dc.identifier.scopus2-s2.0-85090304964
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1002/aoc.6009
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27370
dc.identifier.volume34
dc.identifier.wosWOS:000566752900001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectdegradation
dc.subjectimpregnated alumina catalysts
dc.subjectorganic dyes
dc.subjectPd (II) complexes
dc.subjectreduction
dc.titleThe preparation of new palladium (II) complexes with Schiff base type ligands and its impregnated Al2O3materials: As the catalysts for degradation/reduction of organic dyes
dc.typeArticle

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