(2,6-bis{1-[4-(dimethylamino)phenylimino]ethyl}pyridine)dichlorido(tri-phenylphosphine-?P)ruthenium(II): a zigzag chain of fused centrosymmetric R22(12) rings

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dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoriddayan, osman/0000-0002-0764-1965
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDincer, Muharrem
dc.contributor.authorDayan, Osman
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2025-01-27T20:29:17Z
dc.date.available2025-01-27T20:29:17Z
dc.date.issued2007
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe title compound, [RuCl2(C25H29N5)(C18H15P)], a transfer hydrogenation catalyst, is supported by an N,N',N-tridentate pyridine-bridged ligand and triphenylphosphine. The Run centre is six-coordinated in a distorted octahedral arrangement, with the two Cl atoms located in the axial positions, and the pyridine (py) N atom, the two imino N atoms and the triphenylphosphine P atom located in the equatorial plane. The two equatorial Ru-N-imino distances (mean 2.093 angstrom) are substantially longer than the equatorial Ru-N-py bond [1.954 (4) angstrom]. It is observed that the N-imino-M-N-py bond angle for the five-membered chelate rings of 2,6-bis(imino)pyridine-based complexes is inversely related to the magnitude of the M-N-py bond. The title structure is stabilized by intra- and intermolecular C-H... Cl hydrogen bonds, as well as by intramolecular pi-pi stacking interactions between the aromatic rings belonging to the triphenylphosphine ligand and the dimethylaminophenyl fragment. The intermolecular 2 hydrogen bonds form an R-2(2)(12) ring and a zigzag chain of fused centrosymmetric rings running parallel to the [100] direction.
dc.identifier.doi10.1107/S0108270107021610
dc.identifier.endpageM266
dc.identifier.issn2053-2296
dc.identifier.pmid17551185
dc.identifier.scopus2-s2.0-34250004972
dc.identifier.scopusqualityN/A
dc.identifier.startpageM264
dc.identifier.urihttps://doi.org/10.1107/S0108270107021610
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22896
dc.identifier.volume63
dc.identifier.wosWOS:000247981200011
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInt Union Crystallography
dc.relation.ispartofActa Crystallographica Section C-Structural Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectEthylene Polymerization
dc.subjectRuthenium(Ii) Complexes
dc.subjectCobalt Catalysts
dc.subjectIron
dc.subjectLigands
dc.subjectCyclopropanation
dc.subjectOlefins
dc.title(2,6-bis{1-[4-(dimethylamino)phenylimino]ethyl}pyridine)dichlorido(tri-phenylphosphine-?P)ruthenium(II): a zigzag chain of fused centrosymmetric R22(12) rings
dc.typeArticle

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