First investigation on the photophysical and photochemical properties of azo-bridged phthalocyanine photosensitizers

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Tarih

2016

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Science Bv

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Novel azo-bridged indium(III) acetate phthalocyanine was synthesized by cyclotetramerization reaction of (E)-4-((2,5-dimethoxyphenyl)diazenyl)phthalonitrile. This phthalocyanine was fully characterized by FT-IR, H-1-NMR, UV-vis and MALDI-TOF mass spectroscopic techniques and elemental analyses as well. Additionally, the photophysical and photochemical properties of this phthalocyanine was investigated for the first time. The obtained results were compared with azo-bridged zinc(II) and metal-free phthalocyanine counterparts for determination of central metal effect on these properties. These results were also compared with unsubstituted zinc(II) and indium(III)acetate phthalocyanines for determination of substitution effect on the photophysical and photochemical properties. (C) 2016 Elsevier B.V. All rights reserved.

Açıklama

Anahtar Kelimeler

Dimethoxyphenoxy, Indium(III)acetate phthalocyanine, Azo-bridged, Fluorescence, Singlet oxygen

Kaynak

Journal of Luminescence

WoS Q Değeri

Q2

Scopus Q Değeri

Q1

Cilt

180

Sayı

Künye