Thermal study of ruthenium(II) complexes containing pyridine-2,6-diimines

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dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoriddayan, osman/0000-0002-0764-1965
dc.contributor.authorDogan, F.
dc.contributor.authorDayan, O.
dc.contributor.authorYurekli, M.
dc.contributor.authorCetinkaya, B.
dc.date.accessioned2025-01-27T21:01:54Z
dc.date.available2025-01-27T21:01:54Z
dc.date.issued2008
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThermal behaviors of mono- and binuclear Ru(II)-pydim complexes: [PydimCl(2)RuL] (Pydim: pyridine-2,6-diimine; 2: L=NCMe; 3: L=PPh3) and [PydiMCl(2)Ru(L-L)RuCl(2)Pydim] (4: L-L=pyrazine; 5: L-L=4,4'-bipyridine) have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The decompositions of complexes occur in stepwise. The values of activation energy, Ea, and reaction order, n of the thermal decomposition were calculated by means of several methods such as Coats-Redfern (CR), MacCallum-Tanner (MT), Horowitz-Metzger (HM), van Krevelen (vK), Madhusudanan-Krishnan-Ninan (MKN) and Wanjun-Yuwen-Hen-Cunxin (WYHC) based on the single beating rate. Most appropriate method was determined for each decomposition step according to the least-squares linear regression.
dc.identifier.doi10.1007/s10973-007-8512-y
dc.identifier.endpage949
dc.identifier.issn1388-6150
dc.identifier.issue3
dc.identifier.scopus2-s2.0-45449093983
dc.identifier.scopusqualityQ1
dc.identifier.startpage943
dc.identifier.urihttps://doi.org/10.1007/s10973-007-8512-y
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27227
dc.identifier.volume91
dc.identifier.wosWOS:000254522500042
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectactivation energy
dc.subjectruthenium(II) complexes
dc.subjectthermal behaviour
dc.titleThermal study of ruthenium(II) complexes containing pyridine-2,6-diimines
dc.typeArticle

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