Thermal study of ruthenium(II) complexes containing pyridine-2,6-diimines
dc.authorid | Cetinkaya, Bekir/0000-0002-4551-8650 | |
dc.authorid | dayan, osman/0000-0002-0764-1965 | |
dc.contributor.author | Dogan, F. | |
dc.contributor.author | Dayan, O. | |
dc.contributor.author | Yurekli, M. | |
dc.contributor.author | Cetinkaya, B. | |
dc.date.accessioned | 2025-01-27T21:01:54Z | |
dc.date.available | 2025-01-27T21:01:54Z | |
dc.date.issued | 2008 | |
dc.department | Çanakkale Onsekiz Mart Üniversitesi | |
dc.description.abstract | Thermal behaviors of mono- and binuclear Ru(II)-pydim complexes: [PydimCl(2)RuL] (Pydim: pyridine-2,6-diimine; 2: L=NCMe; 3: L=PPh3) and [PydiMCl(2)Ru(L-L)RuCl(2)Pydim] (4: L-L=pyrazine; 5: L-L=4,4'-bipyridine) have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The decompositions of complexes occur in stepwise. The values of activation energy, Ea, and reaction order, n of the thermal decomposition were calculated by means of several methods such as Coats-Redfern (CR), MacCallum-Tanner (MT), Horowitz-Metzger (HM), van Krevelen (vK), Madhusudanan-Krishnan-Ninan (MKN) and Wanjun-Yuwen-Hen-Cunxin (WYHC) based on the single beating rate. Most appropriate method was determined for each decomposition step according to the least-squares linear regression. | |
dc.identifier.doi | 10.1007/s10973-007-8512-y | |
dc.identifier.endpage | 949 | |
dc.identifier.issn | 1388-6150 | |
dc.identifier.issue | 3 | |
dc.identifier.scopus | 2-s2.0-45449093983 | |
dc.identifier.scopusquality | Q1 | |
dc.identifier.startpage | 943 | |
dc.identifier.uri | https://doi.org/10.1007/s10973-007-8512-y | |
dc.identifier.uri | https://hdl.handle.net/20.500.12428/27227 | |
dc.identifier.volume | 91 | |
dc.identifier.wos | WOS:000254522500042 | |
dc.identifier.wosquality | Q3 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | |
dc.publisher | Springer | |
dc.relation.ispartof | Journal of Thermal Analysis and Calorimetry | |
dc.relation.publicationcategory | info:eu-repo/semantics/openAccess | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.snmz | KA_WoS_20250125 | |
dc.subject | activation energy | |
dc.subject | ruthenium(II) complexes | |
dc.subject | thermal behaviour | |
dc.title | Thermal study of ruthenium(II) complexes containing pyridine-2,6-diimines | |
dc.type | Article |