Synthesis, characterization and application of Ru(II) complexes containing pyridil ligands for dye-sensitized solar cells

dc.authorid0000-0002-0764-1965en_US
dc.authorid0000-0002-1377-5580en_US
dc.authorscopusid13805114500en_US
dc.authorscopusid13405405500en_US
dc.authorwosid-en_US
dc.authorwosid-en_US
dc.contributor.authorDayan, Osman
dc.contributor.authorÖzdemir, Namık
dc.contributor.authorYakuphanoǧlu, Fahrettin
dc.contributor.authorŞerbetci, Zafer
dc.contributor.authorBilici, Ali
dc.date.accessioned2023-04-03T06:46:55Z
dc.date.available2023-04-03T06:46:55Z
dc.date.issued2021en_US
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümü
dc.description.abstractIn this research, a series of Ru(II) complexes, ([Ru(1-7)(ina)(NCS)2] (1-7=5-[6-(5-mercapto-1,3,4-oxadiazol-2-yl)pyridin2-yl]-1,3,4-oxadiazole-2-thiol’s, ina=isonicotinic acid) were synthesized and characterized using different spectroscopic and analytic techniques, such as NMR, UV, IR, CV and CHN. Also, the new complexes were used in dye-sensitized solar cells (DSSC) as sensitizers. Current-voltage characteristics showed that the modifications of ligands clearly affected DSSC yield. Additionally, DFT calculations were performed and showed locations of frontier molecular orbitals of the complexes. While the locations of HOMO and HOMO– 1 orbitals are on Ru(II) metal center and SCN− ligands, the location of LUMO and LUMO+1orbitals are on the 1-7 ligands.en_US
dc.identifier.citationDayan, O., Özdemir, N., Yakuphanoǧlu, F., Şerbetci, Z., & Bilici, A. (2021). Synthesis, characterization and application of ru(II) complexes containing pyridil ligands for dye-sensitized solar cells. Materials Science- Poland, 38(3), 450-458. doi:10.2478/msp-2020-0060en_US
dc.identifier.doi10.2478/msp-2020-0060
dc.identifier.endpage458en_US
dc.identifier.issn2083-134X
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85097601985
dc.identifier.startpage450en_US
dc.identifier.urihttps://doi.org/10.2478/msp-2020-0060
dc.identifier.urihttps://hdl.handle.net/20.500.12428/3879
dc.identifier.volume38en_US
dc.identifier.wosWOS:000600545900012
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorDayan, Osman
dc.institutionauthorBilici, Ali
dc.language.isoen
dc.publisherSciendoen_US
dc.relation.ispartofMaterials Science- Polanden_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.relation.tubitak114Z439
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/us/*
dc.subjectRu(II) complexesen_US
dc.subjectDye-sensitized solar cells (DSSCs)en_US
dc.subjectSensitizeren_US
dc.subjectDFTen_US
dc.subjectCurrent-voltage characteristicsen_US
dc.titleSynthesis, characterization and application of Ru(II) complexes containing pyridil ligands for dye-sensitized solar cells
dc.typeArticle

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