Metal-free and metallo-porphyrazines with eight [5-thiopentyl 2-methoxy-4,6-bis (trifluoromethyl) benzoate] substituent

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dc.contributor.authorGonca, Ergun
dc.date.accessioned2025-01-27T20:20:07Z
dc.date.available2025-01-27T20:20:07Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe reaction of (5-hydroxypentylthio magnesium porphyrazine) with 2-methoxy-4,6-bis(trifluoromethyl)benzoic acid in DCCI and PTSA, esterified MgPz having [5-thiopentyl 2-methoxy-4,6-bis(trifluoromethyl)benzoate] substituent was obtained. Further reactions of the metal-free porphyrazine with M2+(Mg, Co, Cu, Zn, Fe) acetates have produced the metallo-porphyrazines. Finally, by the reaction of FePzCl with pyridine or pyrazine compounds, [FePz(py)(2)] and [FePz(pyz)](n) complexes were prepared as the novel stable complexes, respectively. The target compounds have been characterized by using different spectroscopic methods such as FT-IR, UV-Vis, mass, H-1, C-13, and F-19 NMR together with elemental analysis. The aggregation and the solubility features were indicated in various concentrations and solvents.
dc.description.sponsorshipScientific Research Fund of, Canakkale Onsekiz Mart University [FBA-2014-238]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of, Canakkale Onsekiz Mart University under the Project No. FBA-2014-238.
dc.identifier.doi10.1080/10601325.2017.1309253
dc.identifier.endpage597
dc.identifier.issn1060-1325
dc.identifier.issn1520-5738
dc.identifier.issue9
dc.identifier.scopus2-s2.0-85025121015
dc.identifier.scopusqualityQ2
dc.identifier.startpage589
dc.identifier.urihttps://doi.org/10.1080/10601325.2017.1309253
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21565
dc.identifier.volume54
dc.identifier.wosWOS:000414198200006
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofJournal of Macromolecular Science Part A-Pure and Applied Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPorphyrazine
dc.subject2-methoxy-4,6-bis(trifluoromethyl)benzoic acid
dc.subjectesterification
dc.subjectbisaxial complex
dc.subjectbridged complex
dc.titleMetal-free and metallo-porphyrazines with eight [5-thiopentyl 2-methoxy-4,6-bis (trifluoromethyl) benzoate] substituent
dc.typeArticle

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