Synthesis, thermal, electrochemical and catalytic behavior toward transfer hydrogenation investigations of the half-sandwich RuII complexes with 2-(2?-quinolyl)benzimidazoles

Basit Öğe Kaydı
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.authoridKILINCARSLAN, RAFET/0000-0001-6982-9536
dc.contributor.authorErdem, Ahmet
dc.contributor.authorKilincarslan, Rafet
dc.contributor.authorSahin, Cigdem
dc.contributor.authorDayan, Osman
dc.contributor.authorOzdemir, Namik
dc.date.accessioned2025-01-27T20:14:40Z
dc.date.available2025-01-27T20:14:40Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA series ligands (L3-14) of derived from 2-(2'-quinolyl)benzimidazole (QuBim, L-1) and 2-(2'-quinolyl)-5,6-dimethylbenzimidazole (QuDmBim, L-2) which are an NN-type ligands have been synthesized and characterized with various techniques such as NMR, UV-vis, FT-IR spectroscopy, elemental analysis and X-ray diffraction. The substituted ligands derived from QuBim and QuDmBim have been used as sustaining ligands in the Ru-II-catalyzed transfer hydrogenation (TH) of acetophenone to secondary alcohols in the presence i-PrOH/KOH. The half-sandwich complexes (C1-14) of Ru-II with NN-type ligands have been synthesized by cleavage of [(eta(6)-p-cymene)Ru(mu-Cl)](2) dimer. The resulting complexes have been characterized by NMR, UV-vis, FT-IR spectroscopy and elemental analysis. The thermal and electrochemical properties of selected complexes and ligands were investigated. (C) 2020 Elsevier B.V. All rights reserved.
dc.description.sponsorshipPamukkale University Scientific Research Projects Commission [2014FBE035, 2017FEBE042]; Ondokuz Mayis University [PYO.FEN.1906.19.001]
dc.description.sponsorshipWe acknowledge Pamukkale University Scientific Research Projects Commission (Project No: 2014FBE035 and 2017FEBE042) and Ondokuz Mayis University (Project No: PYO.FEN.1906.19.001) for support. Also, we would like to thank Prof. Dr. Izzet Kara (Pamukkale University, Faculty of Education) for his contribution in making theoretical calculations using Gaussian 16 package and Gauss view 6.
dc.identifier.doi10.1016/j.molstruc.2020.128556
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85086827747
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2020.128556
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21170
dc.identifier.volume1220
dc.identifier.wosWOS:000573566400003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHydrogenation
dc.subjectRu-II complexes
dc.subjectKetones
dc.subjectNN-type ligands
dc.subjectBenzimidazole
dc.subjectPiano-stool complexes
dc.titleSynthesis, thermal, electrochemical and catalytic behavior toward transfer hydrogenation investigations of the half-sandwich RuII complexes with 2-(2?-quinolyl)benzimidazoles
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu