Magnetic colloidal polymeric ionic liquid synthesis and use in hydrogen production

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dc.authoridDemirci, Şahin / 0000-0001-7083-1481
dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridYıldız, Sema / 0000-0003-4760-164X
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorDemir, Şahin
dc.contributor.authorYıldız, Sema
dc.date.accessioned2025-01-27T20:45:25Z
dc.date.available2025-01-27T20:45:25Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractCationic microparticles were synthesized from (3-Acrylamidopropyl)-trimethylammonium chloride (p[APTMACl]) via an inverse suspension polymerization technique. These polymeric microparticles were treated with chloride salt of metals such as CoCl2, NiCl2, CuCl2, FeCl2, and FeCl3 in ethanol. This manuscript reports the ionic liquid (IL) microparticle as templates for in situ metal nanoparticle preparation, and their use as an environmentally benign catalyst system for energy applications. The p(APTMACl) microgels laden with these metal compounds were reduced to their corresponding metallic form with sodium borohydride. Interestingly, Co nanoparticles demonstrated intrinsic magnetic behavior and superior catalytic performance in hydrogen generation from hydrolysis of sodium borohydride (NaBH4) and ammonia borane (NH3BH3). Magnetic properties, zeta potential, particle sizes, and capacity for metal absorption of the p(APTMACl) microparticles were characterized. (C) 2014 Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey [110T649]
dc.description.sponsorshipThis work is supported by the Scientific and Technological Research Council of Turkey (110T649).Also, we appreciate the great support in experimental work from Elif Karacan.
dc.identifier.doi10.1016/j.colsurfa.2014.02.046
dc.identifier.endpage95
dc.identifier.issn0927-7757
dc.identifier.issn1873-4359
dc.identifier.scopus2-s2.0-84896093854
dc.identifier.scopusqualityQ1
dc.identifier.startpage87
dc.identifier.urihttps://doi.org/10.1016/j.colsurfa.2014.02.046
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24557
dc.identifier.volume449
dc.identifier.wosWOS:000335202400011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofColloids and Surfaces A-Physicochemical and Engineering Aspects
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectHydrogel
dc.subjecthydrogen production
dc.subjectmicrogel/nanogel ionic liquid colloids
dc.subjectparticulate ionic liquids
dc.titleMagnetic colloidal polymeric ionic liquid synthesis and use in hydrogen production
dc.typeArticle

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