Syntheses and characterizations of oligo(azomethine ether)s derived from 2,2?-[1,4-enylenebis (methyleneoxy)]dibenzaldehyde and 2,2?-[1,2-phenylenebis (methyleneoxy)]dibenzaldehyde
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Tarih
2012
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The oligo(azomethine ether)s were synthesized via polycondensation of alkyl diamines with aromatic dialdehydes. Two series of dialdehydes, namely 2,2'-[1,2-phenylenebis(methyleneoxy)]dibenzaldehyde [2,2'-1,2-(PBMODB)] and 2,2'-[1,4-phenylenebis(methyleneoxy)]dibenzaldehyde [2,2'-1,4-(PBMODB)] were prepared from the condensation reactions of salicylaldehyde with o-xylenedibromide and p-xylenedibromide, respectively. The structures of dialdehydes and oligomers were determined by FT-IR, H-1-NMR and C-13-NMR. The thermal analyses of oligomers were conducted by DSC and TG/DTA techniques, respectively. Size exclusion chromatography (SEC) technique was also used to determine molecular weights and molecular weight distributions of oligomers. Electrochemical properties of the synthesized products were investigated.
Açıklama
Anahtar Kelimeler
Polyazomethine, Thermal analysis, Dialdehyde, Oligoazomethine
Kaynak
Chinese Journal of Polymer Science
WoS Q Değeri
Q3
Scopus Q Değeri
Q1
Cilt
30
Sayı
5
