An innovative approach to use zeolite as crosslinker for synthesis of p(HEMA-co-NIPAM) hydrogel

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dc.authoridOzay, Hava/0000-0002-4184-7801
dc.authoridOnder, Alper/0000-0002-0775-0053
dc.contributor.authorDurmus, Secil
dc.contributor.authorYilmaz, Betul
dc.contributor.authorOnder, Alper
dc.contributor.authorIlgin, Pinar
dc.contributor.authorOzay, Hava
dc.contributor.authorÖzay, Özgür
dc.date.accessioned2025-01-27T20:44:07Z
dc.date.available2025-01-27T20:44:07Z
dc.date.issued2022
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThis study introduced a modified method to synthesize organic-inorganic hybrid crosslinker based on zeolite. First, zeolite nanoparticles were modified with 3-(aminopropyl)trimethoxysilane. Then, the amine-functionalized zeolite has been reacted with the glycidyl methacrylate via an epoxide ring-opening mechanism. The vinyl-functionalized zeolite was applied as a crosslinking agent to form hydrogel network. A novel temperature-sensitive nanocomposite hydrogel was prepared by crosslinking N-isopropylacrylamide as a comonomer and 2-hydroxyethyl methacrylate as a monomer with free-radical polymerization. Results showed that p(2-hydroxyethyl methacrylate-co-N-isopropylacrylamide)/vinyl-functionalized zeolite nanocomposite hydrogel has a chemically crosslinked and porous network structure. The content of crosslinker and monomers had obvious effects on the swelling ratio of the nanocomposite hydrogel. The temperature and salt-sensitive behavior of the hydrogels are also discussed. We offer a multifunctional crosslinker for preparing sensitive materials that can serve biomedical or environmental applications.
dc.description.sponsorshipCanakkale Onsekiz Mart University Scientific Research Coordination Unit [FBA-2020-3274]
dc.description.sponsorshipThe authors thank the support of the Canakkale Onsekiz Mart University Scientific Research Coordination Unit (project number: FBA-2020-3274).
dc.identifier.doi10.1007/s00706-022-02908-w
dc.identifier.endpage382
dc.identifier.issn0026-9247
dc.identifier.issn1434-4475
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85126847076
dc.identifier.scopusqualityQ2
dc.identifier.startpage369
dc.identifier.urihttps://doi.org/10.1007/s00706-022-02908-w
dc.identifier.urihttps://hdl.handle.net/20.500.12428/24484
dc.identifier.volume153
dc.identifier.wosWOS:000771838000001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Wien
dc.relation.ispartofMonatshefte Fur Chemie
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectMultifunctional composites
dc.subjectSmart materials
dc.subjectHydrogel
dc.subjectZeolite
dc.titleAn innovative approach to use zeolite as crosslinker for synthesis of p(HEMA-co-NIPAM) hydrogel
dc.typeArticle

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