Monomer/polymer Schiff base copper(II) complexes for catalytic oxidative polymerization of 2,2′-dihydroxybiphenyl

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dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridBilici, Ali / 0000-0002-1377-5580
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.contributor.authorBilici, Ali
dc.contributor.authorKaya, İsmet
dc.contributor.authorDoğan, Fatih
dc.date.accessioned2025-01-27T20:29:06Z
dc.date.available2025-01-27T20:29:06Z
dc.date.issued2009
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractCatalytic oxidative polymerization of 2,2'-dihydroxybiphenyl (DHBP) was performed by using both the Schiff base monomer-Cu(II) complex and Schiff base polymer-Cu(II) complex compounds as catalysts and hydrogen peroxide as oxidant, respectively. The dependence of monomer conversion and molecular weight distribution on various reaction parameters, including time, temperature, solvent as well as the amount of catalyst and oxidant were investigated. The structure of the poly-2,2'-dihydroxybiphenyl (PDHBP) was confirmed by UV-vis, IR, H-1 and C-13 NMR spectroscopy techniques. The electrochemical and thermal properties of PDHBP were also studied. DSC data revealed that PDHBP was amorphous. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2977-2984, 2009
dc.identifier.doi10.1002/pola.23370
dc.identifier.endpage2984
dc.identifier.issn0887-624X
dc.identifier.issn1099-0518
dc.identifier.issue12
dc.identifier.scopus2-s2.0-67549132695
dc.identifier.scopusqualityN/A
dc.identifier.startpage2977
dc.identifier.urihttps://doi.org/10.1002/pola.23370
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22826
dc.identifier.volume47
dc.identifier.wosWOS:000266780000002
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofJournal of Polymer Science Part A-Polymer Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectcatalytic oxidative polymerization
dc.subject2,2 '-dihydroxybipbenyl
dc.subjectgel permeation chromatography (GPC)
dc.subjectmetal-polymer complexes
dc.subjectpolymer-metal complex
dc.subjectSchiff base polymer
dc.subjectsynthesis
dc.titleMonomer/polymer Schiff base copper(II) complexes for catalytic oxidative polymerization of 2,2′-dihydroxybiphenyl
dc.typeArticle

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