Highly charged p(4-vinylpyridine-co-vinylimidazole) particles for versatile applications: Biomedical, catalysis and environmental

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dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.authoridÖzay, Özgür / 0000-0001-6589-9844
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorÖzay, Özgür
dc.date.accessioned2025-01-27T20:38:40Z
dc.date.available2025-01-27T20:38:40Z
dc.date.issued2011
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe pH responsive poly(4-vinylpyridine-co-1-vinylimidazole) p(4-VP-co-VI) and magnetic p(4-VP-co-VI) were prepared by microemulsion polymerization and modified with various bromoalkanes to tune the charge and size of the soft particles. The prepared p(4-VP-co-VI) particles were treated with quaternization agents containing various numbers of carbon atoms including HCl, bromoethane (BE), 1-bromobutane (BB), 1-bromohexane (BH), and 2-bromoethylamine (BEA) to generate charges on the nitrogen atom of the polymeric moieties. The versatile usage of the prepared and modified hydrogel particles were demonstrated in various fields: (1) as drug delivery devices using a model drug, naproxene sodium salt (NS), (2) in environmental applications i.e., toxic species removal of an organic species, 4-nitrophenol (4-NP), and a toxic metal, arsenic, and (3) in catalysis by using the prepared p(4-VP-co-VI) hydrogel particle as a template to prepare a Cu (0) metal nanocatalyst in situ for use in the reduction of 4-NP. (C) 2011 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipCanakkale Onsekiz Mart University [COMU-2010/187]; TUBA [2008-TUBA-GEBIP]
dc.description.sponsorshipThis work is supported by Canakkale Onsekiz Mart University (COMU-2010/187). N. Sahiner is grateful for financial support from TUBA under the 2008-TUBA-GEBIP Program.
dc.identifier.doi10.1016/j.reactfunctpolym.2011.03.003
dc.identifier.endpage615
dc.identifier.issn1381-5148
dc.identifier.issue6
dc.identifier.scopus2-s2.0-79953265283
dc.identifier.scopusqualityQ1
dc.identifier.startpage607
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2011.03.003
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23701
dc.identifier.volume71
dc.identifier.wosWOS:000290893800002
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofReactive & Functional Polymers
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectMicrogels
dc.subjectHydrogel nanocomposites
dc.subjectVersatile and modifiable particles
dc.subjectDrug delivery
dc.subjectEnvironmental applications and catalysis
dc.titleHighly charged p(4-vinylpyridine-co-vinylimidazole) particles for versatile applications: Biomedical, catalysis and environmental
dc.typeArticle

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