Fast removal of high quantities of toxic arsenate via cationic p(APTMACl) microgels

dc.authoridDemirci, Şahin / 0000-0001-7083-1481
dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.contributor.authorRehman, Saif Ur
dc.contributor.authorSiddiq, Mohammed
dc.contributor.authorAl-Lohedan, Hamad
dc.contributor.authorAktaş, Nahit
dc.contributor.authorŞahiner, Mehtap
dc.contributor.authorDemirci, Şahin
dc.contributor.authorŞahiner, Nurettin
dc.date.accessioned2025-01-27T20:34:43Z
dc.date.available2025-01-27T20:34:43Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHydrogels are resourceful materials and can be prepared in different morphology, size, surface charge and porosity adopting different polymerization techniques and reaction conditions. The cationic poly(3-acrylamidopropyl)trimethylammonium chloride (p(APTMACl)) microgels were synthesized by photo-initiated inverse suspension polymerization technique. These microgels were utilized as absorbents for the removal of toxic arsenate (As) from different aqueous environments. The experimental parameters affecting absorption efficiency were investigated, and it was demonstrated that these types of microgels are highly efficient in removing arsenate anions from different aqueous environments compared to the previously reported bulk hydrogel, and cryogel of the same material. A removal efficiency of approximately 97.25% was obtained by immersing 0.5 g microgel in 250 ppm 100 mL solution of arsenate anions for 60 min. Both Langmuir and Freundlich adsorption isotherms were applied to adsorption of arsenate anions by p(APTMACl) microgels, and the Langmuir isotherm was a better representation of the adsorption of arsenate with a high value of R-2 (0.9982). Furthermore, mag-p(APTMACl) microgels were synthesized for the adsorption of arsenate anions to provide easy removal of the microgel composite by using an externally applied magnetic field. Furthermore, re-usability of the p(APTMACl) microgels was also investigated for the adsorption of arsenate anions. CD 2015 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipKing Saud University; TUBITAK-BIDEB Program [2216]
dc.description.sponsorshipThe project was full financially supported by King Saud University, through Vice Deanship of Research Chairs. The research fellowship program for international researchers of TUBITAK-BIDEB 2216 Program is gratefully acknowledged.
dc.identifier.doi10.1016/j.jenvman.2015.10.026
dc.identifier.endpage226
dc.identifier.issn0301-4797
dc.identifier.issn1095-8630
dc.identifier.pmid26513320
dc.identifier.scopus2-s2.0-84945307888
dc.identifier.scopusqualityQ1
dc.identifier.startpage217
dc.identifier.urihttps://doi.org/10.1016/j.jenvman.2015.10.026
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23435
dc.identifier.volume166
dc.identifier.wosWOS:000367757200024
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAcademic Press Ltd- Elsevier Science Ltd
dc.relation.ispartofJournal of Environmental Management
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectArsenic removal
dc.subjectCationic microgel/nanogel
dc.subjectMagnetic composite microgel
dc.titleFast removal of high quantities of toxic arsenate via cationic p(APTMACl) microgels
dc.typeArticle

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