Regioselectively functionalized synthesis of poly(amino naphthalene disulfonic acid)

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dc.authoridTemizkan Özdamar, Kevser / 0000-0001-7740-3252
dc.authoridKaya, İsmet / 0000-0002-9813-2962
dc.authoridDoğan, Fatih / 0000-0001-5844-8893
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.contributor.authorTemizkan, Keyser
dc.date.accessioned2025-01-27T20:27:35Z
dc.date.available2025-01-27T20:27:35Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHere, we reported the regioselective formation of poly(amino naphthalene disulfonic acid) (PANDA) nanoparticles by a template-free polymerization process in an aqueous alkaline medium. The NMR, FT-IR, UV-vis, gel permeation chromatography (GPC), thermogravimetry (TG), differential scanning calorimetry (DSC), cyclic voltammetry (CV), photoluminescence (PL), dynamic light scattering (DLS), X-Ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and conductivity techniques were used to investigate the structure characterization in addition to the chemical and physical properties of PANDA polymer-based nanoparticle with molecular weight ca. 14000 Da. Polymer-based nanoparticle showed a reversible redox behavior because of its electroactive nature. PANDA, also, emitted a yellow light while ANDA typically emitted a blue light in DMSO. PANDA displayed an uncommon high photoluminescence quantum efficiency of approximately 30%. The kinetic parameters related to the solid state thermal decomposition of the poly-nanoparticles were calculated from isoconversional methods based on multiple heating rates by TG-DTG/DTA curves. (C) 2016 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.synthmet.2016.02.010
dc.identifier.endpage85
dc.identifier.issn0379-6779
dc.identifier.scopus2-s2.0-84958581327
dc.identifier.scopusqualityQ1
dc.identifier.startpage77
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2016.02.010
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22728
dc.identifier.volume215
dc.identifier.wosWOS:000376839900012
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPolymer-based nanoparticle
dc.subjectOxidative polymerization
dc.subjectPhotoluminescence
dc.subjectThermal stability
dc.titleRegioselectively functionalized synthesis of poly(amino naphthalene disulfonic acid)
dc.typeArticle

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