Synthesis, Characterization, Electrochemical and Surface Morphologies of Polyazomethines Containing Silane and Phosphazene Units

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dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.authoridTemizkan Ozdamar, Kevser/0000-0001-7740-3252
dc.contributor.authorTemizkan, Kevser
dc.contributor.authorKaya, İsmet
dc.date.accessioned2025-01-27T20:29:16Z
dc.date.available2025-01-27T20:29:16Z
dc.date.issued2017
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPolyazomethines containing silane and phosphazene groups were synthesized via elimination reactions of dihydroxy compounds containing imine bonding with phosphazane and silane dichloride. The structures of monomers and polymers containing phosphazane and silane groups were supported by H-1-NMR, C-13-NMR, FT-IR and UV-Vis techniques. Electrochemical properties of the prepared Schiff bases and polymers were given by cyclic voltammetric (CV) analysis. Thermal properties of synthesized monomers and polymers were determined by TG-DTA and TG-DTA, DMA and DSC techniques, respectively. Molecular mass distributions of polymers are determined with gel permeation chromatography (GPC) measurement. Morphologic images of polymers containing heteroatom (silane/phosphazene) and azomethine linkage in the main chain were investigated by SEM techniques. The electrochemical band gap values of SB-1, SB-2, P-1, P-2 and P-3 compounds were found as 3.09, 3.30, 2.63, 3.07 and 3.04 eV, respectively.
dc.identifier.doi10.1007/s10895-017-2104-4
dc.identifier.endpage1677
dc.identifier.issn1053-0509
dc.identifier.issn1573-4994
dc.identifier.issue5
dc.identifier.pmid28512696
dc.identifier.scopus2-s2.0-85019237184
dc.identifier.scopusqualityQ3
dc.identifier.startpage1667
dc.identifier.urihttps://doi.org/10.1007/s10895-017-2104-4
dc.identifier.urihttps://hdl.handle.net/20.500.12428/22891
dc.identifier.volume27
dc.identifier.wosWOS:000409176500016
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherSpringer/Plenum Publishers
dc.relation.ispartofJournal of Fluorescence
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPoly(azomethine)
dc.subjectElectrochemical properties
dc.subjectThermal degradation
dc.subjectFluorescence properties
dc.titleSynthesis, Characterization, Electrochemical and Surface Morphologies of Polyazomethines Containing Silane and Phosphazene Units
dc.typeArticle

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