Dicationic poly(4-vinyl pyridinium) ionic liquid capsules as template for Co nanoparticle preparation and H2 production from hydrolysis of NaBH4
dc.authorid | Yaşar, Alper O. / 0000-0002-1192-9726 | |
dc.authorid | Şahiner, Nurettin / 0000-0003-0120-530X | |
dc.contributor.author | Şahiner, Nurettin | |
dc.contributor.author | Yaşar, Alper O. | |
dc.contributor.author | Aktaş, Nahit | |
dc.date.accessioned | 2025-01-27T20:38:41Z | |
dc.date.available | 2025-01-27T20:38:41Z | |
dc.date.issued | 2015 | |
dc.department | Çanakkale Onsekiz Mart Üniversitesi | |
dc.description.abstract | Poly(4-vinyl pyridine)-silica (p(4-VP)-silica) composites were synthesized via micro emulsion polymerization, and the capsule of p(4-vinyl pyridine), as cap-p(4-VP), was prepared by removing the core silica from p(4-VP)-silica composites by HF treatment. Dicationic particles in the form of cappoly(4-vinyl pyridine)(++)-1,4-butane (cap-p(4-VP)(++)-C-4), capsule-poly(4-vinyl pyridine)(++)-1,6-hexane (cap-p(4-VP)(++)-C-6), and capsule-poly(4-vinyl pyridine)(++)-1,8-octane (cap-p(4-VP)-C-8) were prepared by modifying cap-p(4-VP) particles with corresponding dibromo alkanes. Then, polymer-metal composites were also prepared from cap-p(4-VP) and dicationic cap-p(4-VP) particles by loading CoCl2 from ethanol and the obtained composites were used in H-2 generation from hydrolysis of NaBH4, and The Ea for the composite catalyst was calculated as 56.53 kJ/mol. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. | |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey [110T649] | |
dc.description.sponsorship | This work is supported by the Scientific and Technological Research Council of Turkey (110T649). | |
dc.identifier.doi | 10.1016/j.jiec.2014.07.047 | |
dc.identifier.endpage | 108 | |
dc.identifier.issn | 1226-086X | |
dc.identifier.issn | 1876-794X | |
dc.identifier.scopus | 2-s2.0-85027951608 | |
dc.identifier.scopusquality | Q1 | |
dc.identifier.startpage | 100 | |
dc.identifier.uri | https://doi.org/10.1016/j.jiec.2014.07.047 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12428/23705 | |
dc.identifier.volume | 23 | |
dc.identifier.wos | WOS:000355234900014 | |
dc.identifier.wosquality | Q1 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | |
dc.publisher | Elsevier Science Inc | |
dc.relation.ispartof | Journal of Industrial and Engineering Chemistry | |
dc.relation.publicationcategory | info:eu-repo/semantics/openAccess | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.snmz | KA_WoS_20250125 | |
dc.subject | Capsule p(4-VP) | |
dc.subject | Dicationic particle | |
dc.subject | Hydrogen production | |
dc.subject | Microgel | |
dc.subject | Nanogel | |
dc.title | Dicationic poly(4-vinyl pyridinium) ionic liquid capsules as template for Co nanoparticle preparation and H2 production from hydrolysis of NaBH4 | |
dc.type | Article |
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