Dicationic poly(4-vinyl pyridinium) ionic liquid capsules as template for Co nanoparticle preparation and H2 production from hydrolysis of NaBH4

dc.authoridYaşar, Alper O. / 0000-0002-1192-9726
dc.authoridŞahiner, Nurettin / 0000-0003-0120-530X
dc.contributor.authorŞahiner, Nurettin
dc.contributor.authorYaşar, Alper O.
dc.contributor.authorAktaş, Nahit
dc.date.accessioned2025-01-27T20:38:41Z
dc.date.available2025-01-27T20:38:41Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractPoly(4-vinyl pyridine)-silica (p(4-VP)-silica) composites were synthesized via micro emulsion polymerization, and the capsule of p(4-vinyl pyridine), as cap-p(4-VP), was prepared by removing the core silica from p(4-VP)-silica composites by HF treatment. Dicationic particles in the form of cappoly(4-vinyl pyridine)(++)-1,4-butane (cap-p(4-VP)(++)-C-4), capsule-poly(4-vinyl pyridine)(++)-1,6-hexane (cap-p(4-VP)(++)-C-6), and capsule-poly(4-vinyl pyridine)(++)-1,8-octane (cap-p(4-VP)-C-8) were prepared by modifying cap-p(4-VP) particles with corresponding dibromo alkanes. Then, polymer-metal composites were also prepared from cap-p(4-VP) and dicationic cap-p(4-VP) particles by loading CoCl2 from ethanol and the obtained composites were used in H-2 generation from hydrolysis of NaBH4, and The Ea for the composite catalyst was calculated as 56.53 kJ/mol. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey [110T649]
dc.description.sponsorshipThis work is supported by the Scientific and Technological Research Council of Turkey (110T649).
dc.identifier.doi10.1016/j.jiec.2014.07.047
dc.identifier.endpage108
dc.identifier.issn1226-086X
dc.identifier.issn1876-794X
dc.identifier.scopus2-s2.0-85027951608
dc.identifier.scopusqualityQ1
dc.identifier.startpage100
dc.identifier.urihttps://doi.org/10.1016/j.jiec.2014.07.047
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23705
dc.identifier.volume23
dc.identifier.wosWOS:000355234900014
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Inc
dc.relation.ispartofJournal of Industrial and Engineering Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCapsule p(4-VP)
dc.subjectDicationic particle
dc.subjectHydrogen production
dc.subjectMicrogel
dc.subjectNanogel
dc.titleDicationic poly(4-vinyl pyridinium) ionic liquid capsules as template for Co nanoparticle preparation and H2 production from hydrolysis of NaBH4
dc.typeArticle

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