Chemical oxidative polymerization, optical, electrochemical and kinetic studies of 8-amino-2-naphthol

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dc.authoridDOGAN, fatih/0000-0001-5844-8893
dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.contributor.authorBilici, Ali
dc.contributor.authorYıldırım, Mehmet
dc.date.accessioned2025-01-27T21:01:55Z
dc.date.available2025-01-27T21:01:55Z
dc.date.issued2015
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHere the polymerization of 8-amino-2-naphthol (AN) is reported without use of an additional external template, surfactants or functional dopants. For this, NaOCl and hydrochloride acid solution (1.0 M) were used as oxidant and reaction medium, respectively. The structure of oligomer was elucidated by FT-IR, UV-vis and H-1-NMR techniques. The number average molecular weight of oligomer was found to be 2200Da with a polydispersity index of 1.4 by size exclusion chromatography. This oligomer exhibited a multicolor emission behavior as it was excited at different wavelenghts. Redox states were clarified by cyclic voltammetry (CV) technique and the relationship between anodic/cathodic peak currents vs. scan rates was determined. Thermal analysis and XRD data assigned that the resulting oligomer was in a semi-crystalline form. The activation energy related to the solid state decomposition was calculated from differential and integral non-isothermal methods and the lowest value using Kissinger procedures was determined to be 79.53 kJ/mol in N-2 atmosphere.
dc.identifier.doi10.1007/s10965-015-0737-z
dc.identifier.issn1022-9760
dc.identifier.issn1572-8935
dc.identifier.issue6
dc.identifier.scopus2-s2.0-84929094041
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s10965-015-0737-z
dc.identifier.urihttps://hdl.handle.net/20.500.12428/27228
dc.identifier.volume22
dc.identifier.wosWOS:000355759800001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Polymer Research
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectOxidative polymerization
dc.subjectHydroxynaphthylamine
dc.subjectMultichromism
dc.subjectActivation energy
dc.subjectCyclic voltammetry
dc.titleChemical oxidative polymerization, optical, electrochemical and kinetic studies of 8-amino-2-naphthol
dc.typeArticle

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