Chemical Oxidative Synthesis and Characterization of Poly(8-hydroxyquinoline) Particles

Basit Öğe Kaydı
dc.authoridTemizkan Ozdamar, Kevser/0000-0001-7740-3252
dc.authoridKaya, Ismet/0000-0002-9813-2962
dc.contributor.authorDoğan, Fatih
dc.contributor.authorKaya, İsmet
dc.contributor.authorTemizkan, Kevser
dc.date.accessioned2025-01-27T20:52:06Z
dc.date.available2025-01-27T20:52:06Z
dc.date.issued2014
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe chemical oxidative polymerization (OP) of 8-hydroxyquinoline (HQ) in an organic medium leaded to the formation of the C-2 and C-4 linking poly (8-hydroxyquinoline) (PHQ). The structure of PHQ was confirmed by UV-Vis, FT-IR, and H-1-NMR. The characterization of polymer was performed by TG-DTA, differential scanning calorimetry, dynamic mechanical analysis, dynamic light scattering, size exclusion chromatography, X-ray diffraction, cyclic voltammetry, atomic force microscope, photoluminescence and solubility tests. The fluorescence spectrum of PHQ exhibited an emission peak at approximately 525nm in DMSO. Accordingly, it was found PHQ emitted green light whereas HQ emitted yellow light in DMSO solvent. Optical band gaps (E-g) of PHQ was calculated to be 3.31eV. The electrical conductivities of iodine doped-PHQ and undoped-PHQ were measured with four-point probe technique. Magnetic particles was prepared by chemical precipitation of mixed Fe(II) and Fe(III) salts and modified with HQ by using an in situ chemical oxidation polymerization method in organic medium.
dc.description.sponsorshipTUBITAK Grants Commission [TBAG-109T914]
dc.description.sponsorshipThis work was financially supported by the TUBITAK Grants Commission (Project No: TBAG-109T914).
dc.identifier.doi10.1080/10601325.2014.967081
dc.identifier.endpage961
dc.identifier.issn1060-1325
dc.identifier.issn1520-5738
dc.identifier.issue12
dc.identifier.scopus2-s2.0-84910657580
dc.identifier.scopusqualityQ2
dc.identifier.startpage948
dc.identifier.urihttps://doi.org/10.1080/10601325.2014.967081
dc.identifier.urihttps://hdl.handle.net/20.500.12428/25658
dc.identifier.volume51
dc.identifier.wosWOS:000344863400002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofJournal of Macromolecular Science Part A-Pure and Applied Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectmagnetic particle
dc.subjectPolyquinoline
dc.subjectX-ray photoelectron spectroscopy
dc.subjectchemical oxidative polymerization
dc.titleChemical Oxidative Synthesis and Characterization of Poly(8-hydroxyquinoline) Particles
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu