Synthesis of thermally protective PET–PEG multiblock copolymers as food packaging materials

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Küçük Resim

Tarih

2021

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

SAGE Publications

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

One of the storage conditions affecting quality of food stuffs due to short shelf life is temperature. Thermal insulation can be achieved by adding phase change materials (PCMs) to packaging materials. PCMs store and release latent heat of phase change during melting and crystallization operations, respectively. Thus, they can provide thermal protection for packaged foods. The aim of this study is to prepare new food packaging materials poly (ethylene terephthalate)–poly (ethylene glycol) (PET–PEG) multiblock copolymers as solid–solid phase change materials (SSPCM) as potential food packaging materials with thermal energy storage (TES) property. Polyesterification was carried out with PEG at different average molecular weights (1000, 4000 and 10,000 g/mol), ethylene glycol (EG) and terephthaloyl chloride (TPC). Synthesized PET–PEG multiblock copolymers were characterized using Fourier transform infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC) methods. The crystal structures of PET–PEG multiblock copolymers were characterized by polarized optical microscopy (POM) and their surface properties were determined by performing contact angle tests. TES capacity of the PET–PEG multiblock copolymers was found in range of 26.1–150.5 J/g. Consequently, this study demonstrates the potential of PET–PEG multiblock copolymers suitable for effective thermal preservation in packaging material applications to maintain the quality of packaged food stuffs.

Açıklama

Anahtar Kelimeler

Protective Food Packaging, Solid–Solid Phase Change Material, Polyethylene Terephthalate (PET), Polyethylene Glycol (PEG), Contact Angle Test

Kaynak

Polymers and Polymer Composites

WoS Q Değeri

Q3

Scopus Q Değeri

Cilt

29

Sayı

9_SUPPL

Künye

Güngör Ertuğral, T., & Alkan, C. (2021). Synthesis of thermally protective PET–PEG multiblock copolymers as food packaging materials. Polymers and Polymer Composites, 29(9_suppl), S1125-S1133. doi:10.1177/09673911211045683