Spectroscopic, photophysical and photochemical properties of newly metallo-phthalocyanines containing coumarin derivative

dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.contributor.authorCapkin, Aylin
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorDurmus, Mahmut
dc.contributor.authorBulut, Mustafa
dc.date.accessioned2025-01-27T20:58:04Z
dc.date.available2025-01-27T20:58:04Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe new, well-soluble and non-aggregated peripheral or non-peripheral tetra-ethyl 7-oxy-4,8-dimethylcoumarin-3-propanoate substituted magnesium (II), zinc (II) and indium (III) acetate phthalocyanines were synthesized. They were characterized by widely known spectroscopic methods such as UV-vis, IR, MALDI-TOF Mass, H-1 NMR spectroscopies and elemental analysis. Photophysical and photochemical properties were studied in N, N-dimethylformamide to determine the usability of each of these phthalocyanines as photosensitizers. The influences of the position and presence of the coumarin derivative at the phthalocyanine skeleton and metal' nature in the phthalocyanine cavity on photophysical and photochemical properties were investigated by comparing with previous analogues (magnesium, zinc, and indium phthalocyanines containing coumarin derivative with different functional groups). The spectroscopic, photophysical, photochemical data and results obtained for each of these phthalocyanines show that they may have the potential to be used as photosensitizers in photodynamic therapy. (c) 2020 Elsevier B.V. All rights reserved.
dc.description.sponsorshipResearch Foundation of Marmara University, Commission of Scientific Research (BAPKO) [FEN-CYLP-150513-0182]
dc.description.sponsorshipWe are thankful to the Research Foundation of Marmara University, Commission of Scientific Research (BAPKO), Project: FEN-CYLP-150513-0182.
dc.identifier.doi10.1016/j.molstruc.2020.128145
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85083246728
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2020.128145
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26600
dc.identifier.volume1213
dc.identifier.wosWOS:000532698700002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectCoumarin
dc.subjectPhthalocyanine
dc.subjectPhotosensitizer
dc.subjectMetal type
dc.titleSpectroscopic, photophysical and photochemical properties of newly metallo-phthalocyanines containing coumarin derivative
dc.typeArticle

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