The novel mesityloxy substituted metallo-phthalocyanine dyes with long fluorescence lifetimes and high singlet oxygen quantum yields

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dc.authoridPiskin, Mehmet/0000-0002-4572-4905
dc.authoridGurel, Ekrem/0000-0001-6262-2866
dc.authoridodabas, zafer/0000-0002-0647-0404
dc.contributor.authorGurel, Ekrem
dc.contributor.authorPiskin, Mehmet
dc.contributor.authorAltun, Selcuk
dc.contributor.authorOdabas, Zafer
dc.contributor.authorDurmus, Mahmut
dc.date.accessioned2025-01-27T20:16:30Z
dc.date.available2025-01-27T20:16:30Z
dc.date.issued2016
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractThe synthesis of novel peripheral or non-peripheral tetra-mesityloxy substituted metal-free, zinc and indium phthalocyanines, which are highly soluble in organic solvents, has been achieved. The phthalocyanines have been characterized by UV-vis, IR, MALDI-TOF Mass, H-1 NMR, C-13 NMR spectroscopies and elemental analysis. On their spectroscopic, photochemical and photophysical properties, the effects of the substituent position and the variety of central metal ions in phthalocyanine cavity are also investigated. Photodegradation, singlet oxygen and fluorescence quantum yields, and fluorescence lifetimes in dimethylformamide for the phthalocyanines are described. These properties of the compounds are very useful for photodynamic therapy applications and their high singlet oxygen quantum yields are very important for Type II mechanisms. The phthalocyanines can be appropriate candidates as Type II photosensitizers. (C) 2015 Elsevier B.V. All rights reserved.
dc.description.sponsorshipMarmara University, Commission of Scientific Research Projects (BAPKO) [FEN-C-YLP-041213-0459]
dc.description.sponsorshipWe are thankful to Marmara University, The Commission of Scientific Research Projects (BAPKO) (Project no: FEN-C-YLP-041213-0459).
dc.identifier.doi10.1016/j.jphotochem.2015.09.009
dc.identifier.endpage51
dc.identifier.issn1010-6030
dc.identifier.scopus2-s2.0-84943412913
dc.identifier.scopusqualityQ1
dc.identifier.startpage42
dc.identifier.urihttps://doi.org/10.1016/j.jphotochem.2015.09.009
dc.identifier.urihttps://hdl.handle.net/20.500.12428/21257
dc.identifier.volume315
dc.identifier.wosWOS:000366230700006
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Photochemistry and Photobiology A-Chemistry
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectTrimethylphenoxy
dc.subjectPhthalocyanine
dc.subjectMesityloxy
dc.subjectPhotophysical
dc.subjectPhotochemical
dc.subjectPhotosensitizers
dc.titleThe novel mesityloxy substituted metallo-phthalocyanine dyes with long fluorescence lifetimes and high singlet oxygen quantum yields
dc.typeArticle

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