Palladium(II) complexes assembled on solid materials: as catalysts for the -NO2 (nitro) to -NH2 (amine) reactions

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dc.authoriddayan, serkan/0000-0003-4171-7297
dc.authoridOzdemir, Namik/0000-0003-3371-9874
dc.contributor.authorDayan, Serkan
dc.contributor.authorKayaci, Nilgun
dc.contributor.authorOzdemir, Namik
dc.contributor.authorDayan, Osman
dc.contributor.authorKalaycioglu Ozpozan, Nilgun
dc.date.accessioned2025-01-27T20:35:15Z
dc.date.available2025-01-27T20:35:15Z
dc.date.issued2020
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractHerein, a new series of [PdCl2(L)(2)] complexes where ligands are monodentate amine ligands bearing sulfonamide groups were synthesized, characterized using various techniques such as NMR, FT-IR, UV-Vis, and sc-XRD and investigated for their catalytic performance for the reduction of nitroarenes (2-nitroaniline, 4-nitroaniline, and nitrobenzene) in the presence of NaBH4 in water under heterogeneous conditions. Because the results show that the synthesized complexes are very efficient catalysts, materials using the selected palladium(II) complex supported by multiwall carbon nanotubes, silicon dioxide, and iron(II,III) oxide (Fe3O4) were fabricated by a simple-impregnation methodology, characterized by FT-IR, BET, TEM, and XRD techniques and investigated for their catalytic performance for the same reaction. Thus, a series of supported catalysts was designed with the aim of both enhancing catalytic activity and reducing noble-metal contents. Our findings serve to develop simple catalytic systems and this system can be easily used for catalytic reduction reactions which are the cornerstone of the production of important chemicals. [GRAPHICS] .
dc.identifier.doi10.1007/s00706-020-02679-2
dc.identifier.endpage1548
dc.identifier.issn0026-9247
dc.identifier.issn1434-4475
dc.identifier.issue10
dc.identifier.scopus2-s2.0-85092408317
dc.identifier.scopusqualityQ2
dc.identifier.startpage1533
dc.identifier.urihttps://doi.org/10.1007/s00706-020-02679-2
dc.identifier.urihttps://hdl.handle.net/20.500.12428/23612
dc.identifier.volume151
dc.identifier.wosWOS:000576870500003
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Wien
dc.relation.ispartofMonatshefte Fur Chemie
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20250125
dc.subjectPalladium(ii) complexes
dc.subjectSupported catalysts
dc.subjectNitrobenzene
dc.subjectHydrogenation
dc.titlePalladium(II) complexes assembled on solid materials: as catalysts for the -NO2 (nitro) to -NH2 (amine) reactions
dc.typeArticle

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