A light-detecting Ru(II)/Si heterojunction system involving a binuclear Ru (II) complex with pyridine-2,6-diimine (pydim) ligand

dc.authoridDayan, Osman / 0000-0002-0764-1965
dc.contributor.authorKoç, Mümin Mehmet
dc.contributor.authorDayan, Osman
dc.contributor.authorDere, Ayşegül
dc.contributor.authorÇetinkaya, Bekir
dc.contributor.authorCoşkun, Burhan
dc.contributor.authorYakuphanoğlu, Fahrettin
dc.date.accessioned2025-01-27T20:56:02Z
dc.date.available2025-01-27T20:56:02Z
dc.date.issued2024
dc.departmentÇanakkale Onsekiz Mart Üniversitesi
dc.description.abstractA meticulously detailed chemical procedure was employed to synthesize the Ru (II)-containing pyridine-2,6-diimine (pydim) organometallic complex. The resulting complex was then applied to Al-coated Si wafers using the spin-coating technique, leading to the production of Al/Ru(II) organometallic complex/n-Si/Al photodiodes. The light responsiveness of these photodiodes was demonstrated through the acquisition of I-V and I-t characteristics. Subsequently, essential parameters such as ideality factor, photosensitivity, barrier height, and photoresponse values were evaluated based on the obtained I-V and I-t plots. The calculations yielded ideality factors and barrier heights, resulting in average values of 6.41 and 0.552 eV, respectively. Furthermore, an in-depth analysis of the electrical properties of the diodes was conducted using G-V and C-V assessments, revealing a strong dependence on AC signal frequency. This investigation underscored that the observed frequency-related electrical behaviour is rooted in series resistance and interface states.
dc.description.sponsorshipScientific and Technological Research Council of Turkiye (TUBITAK); Canakkale Onsekiz Mart University Scientic Research Projects Unit [FIA.2023-4451, FBA-2023-4359]; Kirklrareli University Scientific Research Coordination office [KLUBAP 273]
dc.description.sponsorshipOpen access funding provided by the Scientific and Technological Research Council of Turkiye (TUBITAK).The authors would like to acknowledge the support of Canakkale Onsekiz Mart University Scientic Research Projects Unit for this research through FIA.2023-4451 and FBA-2023-4359 grants. Part of the research was supported by Kirklrareli University Scientific Research Coordination office with project number of KLUBAP 273.
dc.identifier.doi10.1007/s10854-024-12885-x
dc.identifier.issn0957-4522
dc.identifier.issn1573-482X
dc.identifier.issue17
dc.identifier.scopus2-s2.0-85195667764
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s10854-024-12885-x
dc.identifier.urihttps://hdl.handle.net/20.500.12428/26280
dc.identifier.volume35
dc.identifier.wosWOS:001248275000004
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Materials Science-Materials in Electronics
dc.relation.publicationcategoryinfo:eu-repo/semantics/openAccess
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20250125
dc.subjectRuthenium(Ii) Complexes
dc.subjectThin-Film
dc.subjectElectrical Characterization
dc.subjectTransfer Hydrogenation
dc.subjectMononuclear
dc.subjectPhotodiode
dc.subjectLayer
dc.titleA light-detecting Ru(II)/Si heterojunction system involving a binuclear Ru (II) complex with pyridine-2,6-diimine (pydim) ligand
dc.typeArticle

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